Iron Complexes in Zeolites as a New Model of Methane Monooxygenase | Sciact - CRIS-system of Boreskov Institute of Catalysis

Iron Complexes in Zeolites as a New Model of Methane Monooxygenase Full article

Journal

Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837

Output data

Year: 1997, Volume: 61, Number: 2, Pages: 251-258 Pages count : 8 DOI: 10.1007/BF02478380

Tags

Iron complexes, Kinetic isotope effect, Methane oxidation, Methanol, Mössbauer spectroscopy, Nitrous oxide, ZSM-5 zeolite

Authors

Panov G.I. ¹ , Sobolev V.I. ¹ , Dubkov K.A. ¹ , Parmon V.N. ¹ , Ovanesyan N.S. ² , Shilov A.E. ² , Shteinman A.A. ²

Affiliations

1	Federal Scientific Center, Boreskov Institute of Catalysis, Novosibirsk 630090, Russia
2	Institute of Chemical Physics in Chernogolovka, Moscow Region, Chemogolovka 142432, Russia

Funding (5)

1	International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union	93-315
2	International Science Foundation	REU 300
3	International Science Foundation	JBD 100
4	Russian Foundation for Basic Research	94-03-08529
5	Russian Foundation for Basic Research	96-03-32985

Iron complexes in the ZSM-5 zeolite matrix (α-centers) are shown to perform single-turnover cycles of methane oxidation to methanol at room temperature when nitrous oxide is used as a source of oxygen. The origin of carbon and oxygen in the product methanol was traced using 13C and 18O isotopes. Probable structure of α-sites as well as mechanistic features of the reaction allow to consider this system as a first successful model of methane monooxygenase.

Panov G.I. , Sobolev V.I. , Dubkov K.A. , Parmon V.N. , Ovanesyan N.S. , Shilov A.E. , Shteinman A.A.
Iron Complexes in Zeolites as a New Model of Methane Monooxygenase
Reaction Kinetics and Catalysis Letters. 1997. V.61. N2. P.251-258. DOI: 10.1007/BF02478380 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Nov 14, 1996
Accepted:	Feb 3, 1997
Published print:	Jul 1, 1997

Web of science:	WOS:A1997XN88600005
Scopus:	2-s2.0-0001293726
Elibrary:	13271086
Chemical Abstracts:	1997:608352
Chemical Abstracts (print):	127:304664
OpenAlex:	W2050009077

DB	Citing
Web of science	146
Scopus	159
Elibrary	154
OpenAlex	160