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Kinetic Peculiarities in the Low-Temperature Oxidation of H2S on Vanadium Catalysts Научная публикация

Журнал Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837
Вых. Данные Год: 2001, Том: 74, Номер: 1, Страницы: 177-184 Страниц : 8 DOI: 10.1023/A:1014180201457
Ключевые слова Catalytic activity, H2S oxidation, Oscillations, Oxygen, Vanadium catalysts
Авторы Kalinkin P.N. 1 , Kovalenko O.N. 1 , Kundo N.N. 1
Организации
1 Boreskov Institute of Catalysis, Novosibirsk 630090, Russia

Информация о финансировании (1)

1 Российский фонд фундаментальных исследований 98-03-32312

Реферат: H2S oxidation by oxygen on catalysts V2O5/Al2O3, V2O5/TiO2, V2O5/Al2O3/TiO2 was studied at temperatures below the sulfur dew point. High activity and the oscillation character of the oxidation were demonstrated by catalysts with low contents of V2O5 (3–5 wt.%). The increase in the V2O5 concentration to 10–20 wt.% results in the reduction of the catalytic activity and oscillation ability. On a pure V2O5 catalyst, the oscillations were not detected. The difference between the catalysts with the high and low concentrations of V2O5 is explained in terms of the structures of the V5+ species formed in the catalysts.
Библиографическая ссылка: Kalinkin P.N. , Kovalenko O.N. , Kundo N.N.
Kinetic Peculiarities in the Low-Temperature Oxidation of H2S on Vanadium Catalysts
Reaction Kinetics and Catalysis Letters. 2001. V.74. N1. P.177-184. DOI: 10.1023/A:1014180201457 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 23 июл. 2001 г.
Принята к публикации: 10 авг. 2001 г.
Опубликована в печати: 1 сент. 2001 г.
Идентификаторы БД:
Web of science: WOS:000172755100023
Scopus: 2-s2.0-0035780566
РИНЦ: 13364050
Chemical Abstracts: 2001:924489
Chemical Abstracts (print): 136:267156
OpenAlex: W2999572051
Цитирование в БД:
БД Цитирований
Web of science 1
Scopus 1
РИНЦ 2
OpenAlex 1
Альметрики: