Kinetic Peculiarities in the Low-Temperature Oxidation of H2S on Vanadium Catalysts Full article
| Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
||
|---|---|---|---|
| Output data | Year: 2001, Volume: 74, Number: 1, Pages: 177-184 Pages count : 8 DOI: 10.1023/A:1014180201457 | ||
| Tags | Catalytic activity, H2S oxidation, Oscillations, Oxygen, Vanadium catalysts | ||
| Authors |
|
||
| Affiliations |
|
Funding (1)
| 1 | Russian Foundation for Basic Research | 98-03-32312 |
Abstract:
H2S oxidation by oxygen on catalysts V2O5/Al2O3, V2O5/TiO2, V2O5/Al2O3/TiO2 was studied at temperatures below the sulfur dew point. High activity and the oscillation character of the oxidation were demonstrated by catalysts with low contents of V2O5 (3–5 wt.%). The increase in the V2O5 concentration to 10–20 wt.% results in the reduction of the catalytic activity and oscillation ability. On a pure V2O5 catalyst, the oscillations were not detected. The difference between the catalysts with the high and low concentrations of V2O5 is explained in terms of the structures of the V5+ species formed in the catalysts.
Cite:
Kalinkin P.N.
, Kovalenko O.N.
, Kundo N.N.
Kinetic Peculiarities in the Low-Temperature Oxidation of H2S on Vanadium Catalysts
Reaction Kinetics and Catalysis Letters. 2001. V.74. N1. P.177-184. DOI: 10.1023/A:1014180201457 WOS Scopus РИНЦ ANCAN OpenAlex
Kinetic Peculiarities in the Low-Temperature Oxidation of H2S on Vanadium Catalysts
Reaction Kinetics and Catalysis Letters. 2001. V.74. N1. P.177-184. DOI: 10.1023/A:1014180201457 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Jul 23, 2001 |
| Accepted: | Aug 10, 2001 |
| Published print: | Sep 1, 2001 |
Identifiers:
| Web of science: | WOS:000172755100023 |
| Scopus: | 2-s2.0-0035780566 |
| Elibrary: | 13364050 |
| Chemical Abstracts: | 2001:924489 |
| Chemical Abstracts (print): | 136:267156 |
| OpenAlex: | W2999572051 |