Sciact
  • EN
  • RU

Catalysts Based on Zirconium Phosphates for Selective Methane Oxidation to Synthesis Gas Научная публикация

Конференция Natural Gas Conversion V : 5th International Natural Gas Conversion Symposium
20-25 авг. 1998 , Giardini Naxos - Taormina
Сборник Natural Gas Conversion V : Proceedings of the 5th International Natural Gas Conversion Symposium, Giardini Naxos - Taormina, Italy, September 20-25, 1998
Сборник, Elsevier. Amsterdam.1998. 979 c. ISBN 9780444829672.
Журнал Studies in Surface Science and Catalysis
ISSN: 0167-2991
Вых. Данные Год: 1998, Том: 119, Страницы: 759-764 Страниц : 6 DOI: 10.1016/S0167-2991(98)80523-5
Ключевые слова CONVERSION
Авторы Pavlova S.N. 1 , Sadykov V.A. 1 , Paukshtis E.A. 1 , Burgina E.B. 1 , Degtyarev S.P. 1 , Kochubei D.I. 1 , Kalinkin A.V. 1 , Saputina N.F. 1 , Maximovskaya R.I. 1 , Zaikovskii V.I. 1 , Roy R. 2 , Agrawal D. 2
Организации
1 Boreskov Institute of Catalysis SD RAN, pr. Lavrentieva, 5
2 Materials Reseach Laboratory, Pennsylvania State University, University Park, PA 16802-4801

Реферат: The catalytic partial oxidation of methane (POM) to syngas conducted at high pressures and temperatures demands active catalysts with high thermal stability [1-2]. Complex zirconium phosphates of a NASICON type structure have a higher sintering resistance and a lower thermal expansion coefficient than conventional supports such as cordierite, t~-A1203, etc. Further, a flexible structure of these framework phosphates allows to incorporate various substituting cations into the lattice [3-5], and, hence, to regulate their acid/base properties important at least for side reactions (coking, methane dimerization etc). Hence, such systems appear to be promising as supports for POM catalysts. In this work, powdered framework zirconium phosphates MeZr4P6024 loaded with LaNiO3, LaNio_x)Rt~Oy, LaNio.x)IrxOy, LaCo(1.x)IrxOy have been studied as catalysts for POM. To elucidate the factors determining their catalytic properties, chemical composition, real structure of the bulk and surface properties of the catalysts and supports have been investigated.
Библиографическая ссылка: Pavlova S.N. , Sadykov V.A. , Paukshtis E.A. , Burgina E.B. , Degtyarev S.P. , Kochubei D.I. , Kalinkin A.V. , Saputina N.F. , Maximovskaya R.I. , Zaikovskii V.I. , Roy R. , Agrawal D.
Catalysts Based on Zirconium Phosphates for Selective Methane Oxidation to Synthesis Gas
В сборнике Natural Gas Conversion V : Proceedings of the 5th International Natural Gas Conversion Symposium, Giardini Naxos - Taormina, Italy, September 20-25, 1998. – Elsevier., 1998. – C.759-764. – ISBN 9780444829672. DOI: 10.1016/S0167-2991(98)80523-5 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Опубликована в печати: 1 янв. 1998 г.
Опубликована online: 2 сент. 2007 г.
Идентификаторы БД:
Web of science: WOS:000076939000123
Scopus: 2-s2.0-4344567694
РИНЦ: 13289719
Chemical Abstracts: 1998:665643
Chemical Abstracts (print): 129:345223
OpenAlex: W125768029
Цитирование в БД:
БД Цитирований
Web of science 9
Scopus 12
РИНЦ 13
OpenAlex 12
Альметрики: