Cobalt Borate Catalysts for Hydrogen Production via Hydrolysis of Sodium Borohydride Научная публикация
Журнал |
Journal of Alloys and Compounds
ISSN: 0925-8388 , E-ISSN: 1873-4669 |
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Вых. Данные | Год: 2012, Том: 513, Страницы: 266-272 Страниц : 7 DOI: 10.1016/j.jallcom.2011.10.033 | ||
Ключевые слова | Cobalt borate, Cobalt boride, Hydrolysis, Sodium borohydride | ||
Авторы |
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Организации |
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Информация о финансировании (2)
1 | Российский фонд фундаментальных исследований | 09-08-00505 |
2 | Российский фонд фундаментальных исследований | 09-08-00546 (01201162781) |
Реферат:
Cobalt borides are known to be active catalysts in NaBH4 hydrolysis. In situ generation of the active cobalt boride phase in sodium borohydride aqueous solutions is accompanied by formation of cobalt borate whose contribution to the overall catalytic activity of the system has not been studied in detail. In this work an amorphous phase of cobalt borate, which transforms to Co2B2O5 upon crystallization, has been synthesized and analyzed. As-synthesized cobalt borate shows high activity in NaBH4 hydrolysis due to its reduction resulting in catalytically active cobalt-containing phase.
Библиографическая ссылка:
Ozerova A.M.
, Simagina V.I.
, Komova O.V.
, Netskina O.V.
, Odegova G.V.
, Bulavchenko O.A.
, Rudina N.A.
Cobalt Borate Catalysts for Hydrogen Production via Hydrolysis of Sodium Borohydride
Journal of Alloys and Compounds. 2012. V.513. P.266-272. DOI: 10.1016/j.jallcom.2011.10.033 WOS Scopus РИНЦ CAPlusCA OpenAlex
Cobalt Borate Catalysts for Hydrogen Production via Hydrolysis of Sodium Borohydride
Journal of Alloys and Compounds. 2012. V.513. P.266-272. DOI: 10.1016/j.jallcom.2011.10.033 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: | 13 июл. 2011 г. |
Принята к публикации: | 12 окт. 2011 г. |
Опубликована online: | 20 окт. 2011 г. |
Опубликована в печати: | 1 февр. 2012 г. |
Идентификаторы БД:
Web of science: | WOS:000298156400048 |
Scopus: | 2-s2.0-83555174838 |
РИНЦ: | 17970488 |
Chemical Abstracts: | 2011:1603335 |
Chemical Abstracts (print): | 156:79076 |
OpenAlex: | W1996476750 |