Cobalt Borate Catalysts for Hydrogen Production via Hydrolysis of Sodium Borohydride Full article
| Journal |
Journal of Alloys and Compounds
ISSN: 0925-8388 , E-ISSN: 1873-4669 |
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| Output data | Year: 2012, Volume: 513, Pages: 266-272 Pages count : 7 DOI: 10.1016/j.jallcom.2011.10.033 | ||
| Tags | Cobalt borate, Cobalt boride, Hydrolysis, Sodium borohydride | ||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Foundation for Basic Research | 09-08-00505 |
| 2 | Russian Foundation for Basic Research | 09-08-00546 (01201162781) |
Abstract:
Cobalt borides are known to be active catalysts in NaBH4 hydrolysis. In situ generation of the active cobalt boride phase in sodium borohydride aqueous solutions is accompanied by formation of cobalt borate whose contribution to the overall catalytic activity of the system has not been studied in detail. In this work an amorphous phase of cobalt borate, which transforms to Co2B2O5 upon crystallization, has been synthesized and analyzed. As-synthesized cobalt borate shows high activity in NaBH4 hydrolysis due to its reduction resulting in catalytically active cobalt-containing phase.
Cite:
Ozerova A.M.
, Simagina V.I.
, Komova O.V.
, Netskina O.V.
, Odegova G.V.
, Bulavchenko O.A.
, Rudina N.A.
Cobalt Borate Catalysts for Hydrogen Production via Hydrolysis of Sodium Borohydride
Journal of Alloys and Compounds. 2012. V.513. P.266-272. DOI: 10.1016/j.jallcom.2011.10.033 WOS Scopus РИНЦ OpenAlex ANCAN
Cobalt Borate Catalysts for Hydrogen Production via Hydrolysis of Sodium Borohydride
Journal of Alloys and Compounds. 2012. V.513. P.266-272. DOI: 10.1016/j.jallcom.2011.10.033 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Submitted: | Jul 13, 2011 |
| Accepted: | Oct 12, 2011 |
| Published online: | Oct 20, 2011 |
| Published print: | Feb 1, 2012 |
Identifiers:
| ≡ Web of science: | WOS:000298156400048 |
| ≡ Scopus: | 2-s2.0-83555174838 |
| ≡ Elibrary: | 17970488 |
| ≡ OpenAlex: | W1996476750 |
| ≡ Chemical Abstracts: | 2011:1603335 |
| ≡ Chemical Abstracts (print): | 156:79076 |