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Cobalt Borate Catalysts for Hydrogen Production via Hydrolysis of Sodium Borohydride Full article

Journal Journal of Alloys and Compounds
ISSN: 0925-8388 , E-ISSN: 1873-4669
Output data Year: 2012, Volume: 513, Pages: 266-272 Pages count : 7 DOI: 10.1016/j.jallcom.2011.10.033
Tags Cobalt borate, Cobalt boride, Hydrolysis, Sodium borohydride
Authors Ozerova A.M. 1 , Simagina V.I. 1 , Komova O.V. 1 , Netskina O.V. 1 , Odegova G.V. 1 , Bulavchenko O.A. 1 , Rudina N.A. 1
Affiliations
1 Boreskov Institute of Catalysis, Pr. Akademika Lavrentieva 5, Novosibirsk 630090, Russian Federation

Funding (2)

1 Russian Foundation for Basic Research 09-08-00505
2 Russian Foundation for Basic Research 09-08-00546 (01201162781)

Abstract: Cobalt borides are known to be active catalysts in NaBH4 hydrolysis. In situ generation of the active cobalt boride phase in sodium borohydride aqueous solutions is accompanied by formation of cobalt borate whose contribution to the overall catalytic activity of the system has not been studied in detail. In this work an amorphous phase of cobalt borate, which transforms to Co2B2O5 upon crystallization, has been synthesized and analyzed. As-synthesized cobalt borate shows high activity in NaBH4 hydrolysis due to its reduction resulting in catalytically active cobalt-containing phase.
Cite: Ozerova A.M. , Simagina V.I. , Komova O.V. , Netskina O.V. , Odegova G.V. , Bulavchenko O.A. , Rudina N.A.
Cobalt Borate Catalysts for Hydrogen Production via Hydrolysis of Sodium Borohydride
Journal of Alloys and Compounds. 2012. V.513. P.266-272. DOI: 10.1016/j.jallcom.2011.10.033 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Jul 13, 2011
Accepted: Oct 12, 2011
Published online: Oct 20, 2011
Published print: Feb 1, 2012
Identifiers:
Web of science: WOS:000298156400048
Scopus: 2-s2.0-83555174838
Elibrary: 17970488
Chemical Abstracts: 2011:1603335
Chemical Abstracts (print): 156:79076
OpenAlex: W1996476750
Citing:
DB Citing
Web of science 71
Scopus 70
Elibrary 67
OpenAlex 76
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