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Effects of the Interaction of Dispersed Metal Particles with the Support in Catalysts Prepared Using Organometallic Compounds. II. (Pt + Pr)/SiO2 System Научная публикация

Журнал Applied Catalysis (up to 1991)
ISSN: 0166-9834
Вых. Данные Год: 1986, Том: 26, Номер: 1-2, Страницы: 327-338 Страниц : 12 DOI: 10.1016/S0166-9834(00)82562-2
Авторы Ryndin Yu.A. 1 , Nogin Yu.N. 1 , Chuvilin A.L. 1 , Pashis A.V. 1 , Zverev Yu.B. 1 , Yermakov Yu.I. 1
Организации
1 Institute of Catalysis

Реферат: The properties of the catalyst (Pt + Pr)/SiO2 prepared by decomposition of anchored complexes of Pr and Pt differ from those of Pt/SiO2 by (1) an increase in the dispersion and thermal stability of platinum, (2) a positive shift of the binding energy of the Pt 4f level by 0.6 eV, (3) a decrease in the specific chemisorption of H2 and a decrease in activity in benzene hydrogenation and ethane hydrogenolysis, but an increase in activity in the synthesis of methanol from CO and H2. The possible reasons for these effects are discussed on the basis of the concept of the direct interaction of Pt particles less than 10Å in size with surface Pr ions.
Библиографическая ссылка: Ryndin Y.A. , Nogin Y.N. , Chuvilin A.L. , Pashis A.V. , Zverev Y.B. , Yermakov Y.I.
Effects of the Interaction of Dispersed Metal Particles with the Support in Catalysts Prepared Using Organometallic Compounds. II. (Pt + Pr)/SiO2 System
Applied Catalysis (up to 1991). 1986. V.26. N1-2. P.327-338. DOI: 10.1016/S0166-9834(00)82562-2 WOS Scopus РИНЦ РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 21 янв. 1986 г.
Принята к публикации: 15 апр. 1986 г.
Опубликована в печати: 15 сент. 1986 г.
Опубликована online: 2 окт. 2001 г.
Идентификаторы БД:
Web of science: WOS:A1986E277700025
Scopus: 2-s2.0-0345229388
РИНЦ: 31100303 | 23753081
Chemical Abstracts: 1986:597737
Chemical Abstracts (print): 105:197737
OpenAlex: W2012319338
Цитирование в БД:
БД Цитирований
Web of science 9
Scopus 10
РИНЦ 9 1
OpenAlex 6
Альметрики: