Effects of the Interaction of Dispersed Metal Particles with the Support in Catalysts Prepared Using Organometallic Compounds. II. (Pt + Pr)/SiO2 System Full article
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Applied Catalysis (up to 1991)
ISSN: 0166-9834 |
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| Output data | Year: 1986, Volume: 26, Number: 1-2, Pages: 327-338 Pages count : 12 DOI: 10.1016/S0166-9834(00)82562-2 | ||
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Abstract:
The properties of the catalyst (Pt + Pr)/SiO2 prepared by decomposition of anchored complexes of Pr and Pt differ from those of Pt/SiO2 by (1) an increase in the dispersion and thermal stability of platinum, (2) a positive shift of the binding energy of the Pt 4f level by 0.6 eV, (3) a decrease in the specific chemisorption of H2 and a decrease in activity in benzene hydrogenation and ethane hydrogenolysis, but an increase in activity in the synthesis of methanol from CO and H2. The possible reasons for these effects are discussed on the basis of the concept of the direct interaction of Pt particles less than 10Å in size with surface Pr ions.
Cite:
Ryndin Y.A.
, Nogin Y.N.
, Chuvilin A.L.
, Pashis A.V.
, Zverev Y.B.
, Yermakov Y.I.
Effects of the Interaction of Dispersed Metal Particles with the Support in Catalysts Prepared Using Organometallic Compounds. II. (Pt + Pr)/SiO2 System
Applied Catalysis (up to 1991). 1986. V.26. N1-2. P.327-338. DOI: 10.1016/S0166-9834(00)82562-2 WOS Scopus РИНЦ РИНЦ OpenAlex ANCAN
Effects of the Interaction of Dispersed Metal Particles with the Support in Catalysts Prepared Using Organometallic Compounds. II. (Pt + Pr)/SiO2 System
Applied Catalysis (up to 1991). 1986. V.26. N1-2. P.327-338. DOI: 10.1016/S0166-9834(00)82562-2 WOS Scopus РИНЦ РИНЦ OpenAlex ANCAN
Dates:
| Submitted: | Jan 21, 1986 |
| Accepted: | Apr 15, 1986 |
| Published print: | Sep 15, 1986 |
| Published online: | Oct 2, 2001 |
Identifiers:
| ≡ Web of science: | WOS:A1986E277700025 |
| ≡ Scopus: | 2-s2.0-0345229388 |
| ≡ Elibrary: | 31100303 | 23753081 |
| ≡ OpenAlex: | W2012319338 |
| ≡ Chemical Abstracts: | 1986:597737 |
| ≡ Chemical Abstracts (print): | 105:197737 |