Carboxylic Acid Transvinylation as Catalysed by Complexes of Palladium Acetate with Phenanthroline-like Ligands Научная публикация
| Журнал |
Applied Catalysis (up to 1991)
ISSN: 0166-9834 |
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| Вых. Данные | Год: 1990, Том: 66, Номер: 1, Страницы: 123-132 Страниц : 9 DOI: 10.1016/S0166-9834(00)81632-2 | ||
| Ключевые слова | complex catalysts, palladium acetate, phenanthroline, selectivity (vinylation), transvinylation, vinylation | ||
| Авторы |
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| Организации |
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Реферат:
The complexing of palladium acetate with di-imine ligands results in a promotion effect on the vinyl exchange processes and ensures excellent selectivity and stability of the catalyst under reaction conditions. Vinylation of both saturated and unsaturated car☐ylic acids by vinyl acetate proceeds smoothly with such catalysts even at an increased concentration of water in the reaction mixture. Catalytic activity is dependent on the structure of the chelate ligand, with a steric factor playing a predominant role. A kinetic study has been performed and a reaction mechanism is proposed.
Библиографическая ссылка:
Ketterling A.A.
, Lisitsyn A.S.
, Nosov A.V.
, Likholobov V.A.
Carboxylic Acid Transvinylation as Catalysed by Complexes of Palladium Acetate with Phenanthroline-like Ligands
Applied Catalysis (up to 1991). 1990. V.66. N1. P.123-132. DOI: 10.1016/S0166-9834(00)81632-2 WOS Scopus РИНЦ OpenAlex CAPlusCA
Carboxylic Acid Transvinylation as Catalysed by Complexes of Palladium Acetate with Phenanthroline-like Ligands
Applied Catalysis (up to 1991). 1990. V.66. N1. P.123-132. DOI: 10.1016/S0166-9834(00)81632-2 WOS Scopus РИНЦ OpenAlex CAPlusCA
Даты:
| Поступила в редакцию: | 10 мар. 1989 г. |
| Принята к публикации: | 20 апр. 1990 г. |
| Опубликована в печати: | 5 нояб. 1990 г. |
| Опубликована online: | 2 окт. 2001 г. |
Идентификаторы БД:
| ≡ Web of science: | WOS:A1990EK66000012 |
| ≡ Scopus: | 2-s2.0-0025701236 |
| ≡ РИНЦ: | 31086076 |
| ≡ OpenAlex: | W2058086807 |
| ≡ Chemical Abstracts: | 1991:64732 |
| ≡ Chemical Abstracts (print): | 114:64732 |