Carboxylic Acid Transvinylation as Catalysed by Complexes of Palladium Acetate with Phenanthroline-like Ligands | Sciact - CRIS-система Института катализа

Carboxylic Acid Transvinylation as Catalysed by Complexes of Palladium Acetate with Phenanthroline-like Ligands Научная публикация

Журнал

Applied Catalysis (up to 1991)
ISSN: 0166-9834

Вых. Данные

Год: 1990, Том: 66, Номер: 1, Страницы: 123-132 Страниц : 9 DOI: 10.1016/S0166-9834(00)81632-2

Ключевые слова

complex catalysts, palladium acetate, phenanthroline, selectivity (vinylation), transvinylation, vinylation

Авторы

Ketterling A.A. ¹ , Lisitsyn A.S. ¹ , Nosov A.V. ¹ , Likholobov V.A. ¹

Организации

1	Institute of Catalysis, Novosibirsk 630090 (U.S.S.R.)

The complexing of palladium acetate with di-imine ligands results in a promotion effect on the vinyl exchange processes and ensures excellent selectivity and stability of the catalyst under reaction conditions. Vinylation of both saturated and unsaturated car☐ylic acids by vinyl acetate proceeds smoothly with such catalysts even at an increased concentration of water in the reaction mixture. Catalytic activity is dependent on the structure of the chelate ligand, with a steric factor playing a predominant role. A kinetic study has been performed and a reaction mechanism is proposed.

Ketterling A.A. , Lisitsyn A.S. , Nosov A.V. , Likholobov V.A.
Carboxylic Acid Transvinylation as Catalysed by Complexes of Palladium Acetate with Phenanthroline-like Ligands
Applied Catalysis (up to 1991). 1990. V.66. N1. P.123-132. DOI: 10.1016/S0166-9834(00)81632-2 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	10 мар. 1989 г.
Принята к публикации:	20 апр. 1990 г.
Опубликована в печати:	5 нояб. 1990 г.
Опубликована online:	2 окт. 2001 г.

Web of science:	WOS:A1990EK66000012
Scopus:	2-s2.0-0025701236
РИНЦ:	31086076
Chemical Abstracts:	1991:64732
Chemical Abstracts (print):	114:64732
OpenAlex:	W2058086807

БД	Цитирований
Web of science	11
Scopus	12
РИНЦ	11
OpenAlex	13