Mechanism of Catalytic Oxidation of Olefins by Periodic Acid in Acetic Solutions of Palladium Acetate Научная публикация
| Журнал |
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic)
ISSN: 0304-5102 |
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| Вых. Данные | Год: 1986, Том: 38, Номер: 3, Страницы: 263-271 Страниц : 9 DOI: 10.1016/0304-5102(86)85032-5 | ||
| Ключевые слова | CATALYSIS - Reaction Kinetics; CATALYSTS - Palladium Compounds; ETHYLENE - Oxidation; NUCLEAR MAGNETIC RESONANCE; SPECTROSCOPY, INFRARED | ||
| Авторы |
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| Организации |
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Реферат:
Oxidation of C2-C4 olefins by periodic acid, catalyzed with palladium acetate, is studied. During oxidation, glycol esters are formed with high selectivity. The process is accompanied by oxygen atom transfer from the periodate anion to the olefin. Results of the kinetic study of ethylene oxidation are reported. The structure of intermediate palladium complexes is studied using NMR and IR spectroscopy. The mechanism of the reaction is also discussed.
Библиографическая ссылка:
Kuznetsova N.I.
, Fedotov M.A.
, Likholobov V.A.
, Yermakov Y.I.
Mechanism of Catalytic Oxidation of Olefins by Periodic Acid in Acetic Solutions of Palladium Acetate
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic). 1986. V.38. N3. P.263-271. DOI: 10.1016/0304-5102(86)85032-5 WOS Scopus РИНЦ CAPlusCA OpenAlex
Mechanism of Catalytic Oxidation of Olefins by Periodic Acid in Acetic Solutions of Palladium Acetate
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic). 1986. V.38. N3. P.263-271. DOI: 10.1016/0304-5102(86)85032-5 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 8 янв. 1986 г. |
| Принята к публикации: | 28 мая 1986 г. |
| Опубликована в печати: | 1 дек. 1986 г. |
| Опубликована online: | 2 окт. 2001 г. |
Идентификаторы БД:
| Web of science: | WOS:A1986F261300004 |
| Scopus: | 2-s2.0-0022893976 |
| РИНЦ: | 30953985 |
| Chemical Abstracts: | 1987:438946 |
| Chemical Abstracts (print): | 107:38946 |
| OpenAlex: | W2000787602 |