Mechanism of Catalytic Oxidation of Olefins by Periodic Acid in Acetic Solutions of Palladium Acetate | Sciact - CRIS-system of Boreskov Institute of Catalysis

Mechanism of Catalytic Oxidation of Olefins by Periodic Acid in Acetic Solutions of Palladium Acetate Full article

Journal

Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic)
ISSN: 0304-5102

Output data

Year: 1986, Volume: 38, Number: 3, Pages: 263-271 Pages count : 9 DOI: 10.1016/0304-5102(86)85032-5

Tags

CATALYSIS - Reaction Kinetics; CATALYSTS - Palladium Compounds; ETHYLENE - Oxidation; NUCLEAR MAGNETIC RESONANCE; SPECTROSCOPY, INFRARED

Authors

Kuznetsova N.I. ¹ , Fedotov M.A. ¹ , Likholobov V.A. ¹ , Yermakov Yu.I. ¹

Affiliations

1	Institute of Catalysis

Oxidation of C2-C4 olefins by periodic acid, catalyzed with palladium acetate, is studied. During oxidation, glycol esters are formed with high selectivity. The process is accompanied by oxygen atom transfer from the periodate anion to the olefin. Results of the kinetic study of ethylene oxidation are reported. The structure of intermediate palladium complexes is studied using NMR and IR spectroscopy. The mechanism of the reaction is also discussed.

Kuznetsova N.I. , Fedotov M.A. , Likholobov V.A. , Yermakov Y.I.
Mechanism of Catalytic Oxidation of Olefins by Periodic Acid in Acetic Solutions of Palladium Acetate
Journal of Molecular Catalysis (Continued after 1994 as Journal of Molecular Catalysis A: Chemical and Journal of Molecular Catalysis B: Enzymatic). 1986. V.38. N3. P.263-271. DOI: 10.1016/0304-5102(86)85032-5 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Jan 8, 1986
Accepted:	May 28, 1986
Published print:	Dec 1, 1986
Published online:	Oct 2, 2001

Web of science:	WOS:A1986F261300004
Scopus:	2-s2.0-0022893976
Elibrary:	30953985
Chemical Abstracts:	1987:438946
Chemical Abstracts (print):	107:38946
OpenAlex:	W2000787602

DB	Citing
Web of science	8
Scopus	10
Elibrary	9
OpenAlex	10