Isotopic Nitrogen Exchange and Ammonia Synthesis on Uranium Nitride | Sciact - CRIS-система Института катализа

Isotopic Nitrogen Exchange and Ammonia Synthesis on Uranium Nitride Научная публикация

Журнал

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Вых. Данные

Год: 1984, Том: 25, Номер: 1, Страницы: 101-106 Страниц : 6

Авторы

Panov G.I. ¹ , Boreskov G.K. ¹ , Kharitonov A.S. ¹ , Moroz E.M. ¹ , Sobolev V.I. ¹

Организации

1	Institute of Catalysis, Siberian Branch U.S.S.R. Academy of Sciences

The catalytic properties of samples of uranium nitride of different chemical composition, alpha-U2N3 and UN1.70, are compared. In both cases, isotopic exchange occurs via the reversible, dissociative adsorption of nitrogen. Despite the similarity of the structural and thermodynamic properties of the phases, the heat of adsorption of nitrogen differs by 120 kj/mole. This leads to a marked difference in the catalytic properties of the samples. It is shown that isotopic exchange serves as a reliable characteristic of molecular nitrogen activation and its ability to enter into ammonia synthesis.

Panov G.I. , Boreskov G.K. , Kharitonov A.S. , Moroz E.M. , Sobolev V.I.
Isotopic Nitrogen Exchange and Ammonia Synthesis on Uranium Nitride
Kinetics and Catalysis. 1984. V.25. N1. P.101-106. WOS Scopus РИНЦ

Панов Г.И. , Боресков Г.К. , Харитонов А.С. , Мороз Э.М. , Соболев В.И.
Изотопный обмен азота и синтез аммиака на нитриде урана
Кинетика и катализ. 1984. Т.25. №1. С.123-129. РИНЦ CAPlusCA

Поступила в редакцию:	6 сент. 1982 г.
Опубликована в печати:	1 янв. 1984 г.

Web of science:	WOS:A1984TN29700001
Scopus:	2-s2.0-0021178944
РИНЦ:	30603152

БД	Цитирований
Web of science	1