Kinetic Model of Catalytic Reduction of Sulfur Dioxide to Hydrogen Sulfide | Sciact - CRIS-система Института катализа

Kinetic Model of Catalytic Reduction of Sulfur Dioxide to Hydrogen Sulfide Научная публикация

Журнал

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Вых. Данные

Год: 1993, Том: 34, Номер: 5, Страницы: 756-764 Страниц : 9

Ключевые слова

HIGH-TEMPERATURE REDUCTION; METHANE

Авторы

Ermakova A. ¹ , Anikeev V.I. ¹ , Bobrin A.S. ¹

Организации

1	Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 5, Novosibirsk, 630090 Russia

Kinetics of complete catalytic reduction of sulfur dioxide by methane in the presence of a γ-Al2O3 catalyst was studied in a flow-type laboratory installation. Mixtures containing 8 - 9% of oxygen and 12 - 15% of SO2 (by volume) were used to simulate the composition of ''strong'' metallurgic exhaust gases. Data obtained enable one to determine the most important chemical reactions occurring at 650 - 850°C in the system under investigation. Results of thermodynamic analysis are also reported. The kinetic model is formulated, and the numerical values of the rate constants and activation energies are estimated for a number of reactions in the course of model identification.

Ermakova A. , Anikeev V.I. , Bobrin A.S.
Kinetic Model of Catalytic Reduction of Sulfur Dioxide to Hydrogen Sulfide
Kinetics and Catalysis. 1993. V.34. N5. P.756-764. WOS РИНЦ

Ермакова А. , Аникеев В.И. , Бобрин А.С.
Кинетическая модель реакции каталитического восстановления диоксида серы до сероводорода
Кинетика и катализ. 1993. Т.34. №5. С.843-851. РИНЦ CAPlusCA

Поступила в редакцию:

11 июн. 1992 г.

Web of science:	WOS:A1993MW17100018
РИНЦ:	30598173

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