Catalytic Reduction of Thiophenes of Petroleum Origin to Thiacycloalkanes by Hydrogen | Sciact - CRIS-система Института катализа

Catalytic Reduction of Thiophenes of Petroleum Origin to Thiacycloalkanes by Hydrogen Научная публикация

Журнал

Petroleum Chemistry: U.S.S.R (up to 1991)
ISSN: 0031-6458

Вых. Данные

Год: 1988, Том: 28, Номер: 1, Страницы: 65-72 Страниц : 8 DOI: 10.1016/0031-6458(88)90032-9

Авторы

Zirka A.A. ^1,2,3,4 , Lyapina N.K. ^1,2,3,4 , Parfenova M.A. ^1,2,3,4 , Masagutov R.M. ^1,2,3,4 , Sharipov A.K. ^1,2,3,4 , Suleimanova Z.A. ^1,2,3,4 , Ryzhova G.L. ^1,2,3,4 , Slizhov Y.G. ^1,2,3,4 , Mashkina A.V. ^1,2,3,4

Организации

1	Tomsk State University
2	Institute of Chemistry, U.S.S.R. Academy of Sciences (Ufa)
3	Institute of Catalysis, U.S.S.R. Academy of Sciences
4	Scientific Research Institute for Petrochemical Processes (NIINeftekhim)

1. Oxidation of dimethylsulphide using atmospheric oxygen at 120° to 150°C was studied under a pressure of 2 to 5 MPa in the presence of a copper phenate catalyst (output up to 1000 mole dimethylsulphoxide calculated as 1 g·atm Cu/hr). 2. Kinetic equations established that the reaction for oxygen is zero order and for dimethylsulphide, first order. Selectivity for dimethylsulphoxide is close to 100%, independent of reaction conditions at a dimethylsulphide conversion lower than 80%; at higher conversions secondary reactions of oxidation of dimethylsulphoxide take place.

Zirka A.A. , Lyapina N.K. , Parfenova M.A. , Masagutov R.M. , Sharipov A.K. , Suleimanova Z.A. , Ryzhova G.L. , Slizhov Y.G. , Mashkina A.V.
Catalytic Reduction of Thiophenes of Petroleum Origin to Thiacycloalkanes by Hydrogen
Petroleum Chemistry: U.S.S.R (up to 1991). 1988. V.28. N1. P.65-72. DOI: 10.1016/0031-6458(88)90032-9 WOS Scopus РИНЦ OpenAlex

Зирка А.А. , Ляпина Н.К. , Парфенова М.А. , Масагутов Р.М. , Шарипов А.Х. , Сулейманова З.А. , Рыжова Г.Л. , Слижов Ю.Г. , Машкина А.В.
Каталитическое восстановление тиофенов нефтяного происхождения водородом до тиациклоалканов
Нефтехимия. 1988. Т.28. №2. С.271-276. РИНЦ CAPlusCA

Поступила в редакцию:	27 апр. 1987 г.
Опубликована в печати:	1 янв. 1988 г.
Опубликована online:	1 апр. 2004 г.

Web of science:	WOS:A1988CV95400011
Scopus:	2-s2.0-45549115922
РИНЦ:	30901772
OpenAlex:	W2063432789

Пока нет цитирований