Autocatalytic Gas-Phase Dehydrogenation of Ethane Обзор
| Журнал |
Research on Chemical Intermediates
ISSN: 0922-6168 , E-ISSN: 1568-5675 |
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| Вых. Данные | Год: 2012, Том: 38, Страницы: 1133-1147 Страниц : 15 DOI: 10.1007/s11164-011-0449-x | ||
| Ключевые слова | Autocatalysis, Ethane pyrolysis, Ethylene biradical, Laser irradiation | ||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Совет по грантам Президента Российской Федерации | НШ-3156.2010.3 |
Реферат:
Homogeneous gas-phase pyrolysis of ethane by continuous CO2 laser irradiation was used in our experiments for bulk heating of the reaction mixture. Laser energy was absorbed by ethylene, the main product of ethane dehydrogenation, and transferred to the reaction medium via collisional relaxation. A mechanism of ethane dehydrogenation is suggested to describe the pyrolysis process. The mechanism is autocatalytic in respect of ethylene and includes ethane–ethylene interaction with the formation of methyl and propyl radicals. Rate constants of elementary reactions, selectivity, and yields of pyrolysis products were determined. The composition of ethane dehydrogenation products determined in the experiments was substantially different from the calculated thermodynamic equilibrium composition.
Библиографическая ссылка:
Snytnikov V.N.
, Mishchenko T.I.
, Snytnikov V.N.
, Malykhin S.E.
, Avdeev V.I.
, Parmon V.N.
Autocatalytic Gas-Phase Dehydrogenation of Ethane
Research on Chemical Intermediates. 2012. V.38. P.1133-1147. DOI: 10.1007/s11164-011-0449-x WOS Scopus РИНЦ CAPlusCA OpenAlex
Autocatalytic Gas-Phase Dehydrogenation of Ethane
Research on Chemical Intermediates. 2012. V.38. P.1133-1147. DOI: 10.1007/s11164-011-0449-x WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 6 окт. 2011 г. |
| Принята к публикации: | 28 нояб. 2011 г. |
| Опубликована online: | 16 дек. 2011 г. |
| Опубликована в печати: | 1 мар. 2012 г. |
Идентификаторы БД:
| Web of science: | WOS:000302146500040 |
| Scopus: | 2-s2.0-84862683692 |
| РИНЦ: | 17992432 |
| Chemical Abstracts: | 2011:1622843 |
| Chemical Abstracts (print): | 156:230097 |
| OpenAlex: | W2065986152 |