Autocatalytic Gas-Phase Dehydrogenation of Ethane Review
| Journal |
Research on Chemical Intermediates
ISSN: 0922-6168 , E-ISSN: 1568-5675 |
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| Output data | Year: 2012, Volume: 38, Pages: 1133-1147 Pages count : 15 DOI: 10.1007/s11164-011-0449-x | ||
| Tags | Autocatalysis, Ethane pyrolysis, Ethylene biradical, Laser irradiation | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Council for Grants of the President of the Russian Federation | НШ-3156.2010.3 |
Abstract:
Homogeneous gas-phase pyrolysis of ethane by continuous CO2 laser irradiation was used in our experiments for bulk heating of the reaction mixture. Laser energy was absorbed by ethylene, the main product of ethane dehydrogenation, and transferred to the reaction medium via collisional relaxation. A mechanism of ethane dehydrogenation is suggested to describe the pyrolysis process. The mechanism is autocatalytic in respect of ethylene and includes ethane–ethylene interaction with the formation of methyl and propyl radicals. Rate constants of elementary reactions, selectivity, and yields of pyrolysis products were determined. The composition of ethane dehydrogenation products determined in the experiments was substantially different from the calculated thermodynamic equilibrium composition.
Cite:
Snytnikov V.N.
, Mishchenko T.I.
, Snytnikov V.N.
, Malykhin S.E.
, Avdeev V.I.
, Parmon V.N.
Autocatalytic Gas-Phase Dehydrogenation of Ethane
Research on Chemical Intermediates. 2012. V.38. P.1133-1147. DOI: 10.1007/s11164-011-0449-x WOS Scopus РИНЦ ANCAN OpenAlex
Autocatalytic Gas-Phase Dehydrogenation of Ethane
Research on Chemical Intermediates. 2012. V.38. P.1133-1147. DOI: 10.1007/s11164-011-0449-x WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Oct 6, 2011 |
| Accepted: | Nov 28, 2011 |
| Published online: | Dec 16, 2011 |
| Published print: | Mar 1, 2012 |
Identifiers:
| Web of science: | WOS:000302146500040 |
| Scopus: | 2-s2.0-84862683692 |
| Elibrary: | 17992432 |
| Chemical Abstracts: | 2011:1622843 |
| Chemical Abstracts (print): | 156:230097 |
| OpenAlex: | W2065986152 |