Redox Mechanism of Acrolein Oxidation over the Product of Molybdophosphoric Heteropolyacid Thermolysis: PMo12O38.5 Научная публикация
| Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Вых. Данные | Год: 1994, Том: 52, Номер: 1, Страницы: 73-80 Страниц : 8 DOI: 10.1007/BF02129852 | ||
| Ключевые слова | Oxidation; Oxygen; Physical Chemistry; Catalysis; Calorimetry | ||
| Авторы |
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| Организации |
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Реферат:
Redox mechanism of oxygen insertion into acrolein upon its oxidation by molecular oxygen on PMo12O38.5 catalyst has been studied. The latter is the product of thermolysis of the series 12 molybdophosphoric heteropolyacid. The heat of oxygen adsorption on the catalyst surface was measured by calorimetry as a function of catalyst reduction by carbon oxide. The value amounted to 72.5±2.5 kcal/mol O2 and did not depend on the reduction degree, which was about 3.5 oxygen monolayers.
Библиографическая ссылка:
Andrushkevich T.V.
, Bondareva V.M.
, Popova G.Y.
, Pankratiev Y.D.
Redox Mechanism of Acrolein Oxidation over the Product of Molybdophosphoric Heteropolyacid Thermolysis: PMo12O38.5
Reaction Kinetics and Catalysis Letters. 1994. V.52. N1. P.73-80. DOI: 10.1007/BF02129852 WOS Scopus РИНЦ CAPlusCA OpenAlex
Redox Mechanism of Acrolein Oxidation over the Product of Molybdophosphoric Heteropolyacid Thermolysis: PMo12O38.5
Reaction Kinetics and Catalysis Letters. 1994. V.52. N1. P.73-80. DOI: 10.1007/BF02129852 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 22 июл. 1993 г. |
| Принята к публикации: | 4 авг. 1993 г. |
| Опубликована в печати: | 1 апр. 1994 г. |
Идентификаторы БД:
| Web of science: | WOS:A1994NU89700010 |
| Scopus: | 2-s2.0-0028407752 |
| РИНЦ: | 31085007 |
| Chemical Abstracts: | 1995:41421 |
| Chemical Abstracts (print): | 122:9297 |
| OpenAlex: | W1978725500 |