Redox Mechanism of Acrolein Oxidation over the Product of Molybdophosphoric Heteropolyacid Thermolysis: PMo12O38.5 Full article
| Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Output data | Year: 1994, Volume: 52, Number: 1, Pages: 73-80 Pages count : 8 DOI: 10.1007/BF02129852 | ||
| Tags | Oxidation; Oxygen; Physical Chemistry; Catalysis; Calorimetry | ||
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Abstract:
Redox mechanism of oxygen insertion into acrolein upon its oxidation by molecular oxygen on PMo12O38.5 catalyst has been studied. The latter is the product of thermolysis of the series 12 molybdophosphoric heteropolyacid. The heat of oxygen adsorption on the catalyst surface was measured by calorimetry as a function of catalyst reduction by carbon oxide. The value amounted to 72.5±2.5 kcal/mol O2 and did not depend on the reduction degree, which was about 3.5 oxygen monolayers.
Cite:
Andrushkevich T.V.
, Bondareva V.M.
, Popova G.Y.
, Pankratiev Y.D.
Redox Mechanism of Acrolein Oxidation over the Product of Molybdophosphoric Heteropolyacid Thermolysis: PMo12O38.5
Reaction Kinetics and Catalysis Letters. 1994. V.52. N1. P.73-80. DOI: 10.1007/BF02129852 WOS Scopus РИНЦ ANCAN OpenAlex
Redox Mechanism of Acrolein Oxidation over the Product of Molybdophosphoric Heteropolyacid Thermolysis: PMo12O38.5
Reaction Kinetics and Catalysis Letters. 1994. V.52. N1. P.73-80. DOI: 10.1007/BF02129852 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Jul 22, 1993 |
| Accepted: | Aug 4, 1993 |
| Published print: | Apr 1, 1994 |
Identifiers:
| Web of science: | WOS:A1994NU89700010 |
| Scopus: | 2-s2.0-0028407752 |
| Elibrary: | 31085007 |
| Chemical Abstracts: | 1995:41421 |
| Chemical Abstracts (print): | 122:9297 |
| OpenAlex: | W1978725500 |