1H NMR Study of the Mechanism of Ethyleneglycol Monoacetate Formation in Oxidative Acetoxylation of Ethylene Catalyzed by Pd(II) Complexes Научная публикация
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New Developments in Selective Oxidation: International Symposium 18-22 сент. 1989 , Rimini |
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| Сборник | New Developments in Selective Oxidation : Proceedings of an International Symposium, Rimini, Italy, September 18-22, 1989 Сборник, 1990. 891 c. ISBN 9780444886941. |
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| Журнал |
Studies in Surface Science and Catalysis
ISSN: 0167-2991 |
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| Вых. Данные | Год: 1990, Том: 55, Страницы: 213-220 Страниц : 8 DOI: 10.1016/S0167-2991(08)60151-2 | ||
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Реферат:
A detailed mechanism of ethylene oxidation by Pd(NOn)CIL2 complexes (n=2,3; L=CD3CN) in a chloroform-acetic acid nmixture is studied by 1H N M R spectroscopy. The end reaction products are ethyleneglycol monoacetate (EGMA), acetaldehyde, nitroethylene and compounds with the general formula CH3-CHXY (X, Y = OH, OAc, Cl, NO2), whose ratio depends upon the solvent composition. Kinetic and spectral data obtained indicate the formation of a number of intermediates. The structure and routes of decomposition of the intermediates to EGMA and other reaction products are suggested.
Библиографическая ссылка:
Gusevskaya E.V.
, Beck I.E.
, Stepanov A.G.
, Likholobov V.A.
, Zamaraev K.I.
1H NMR Study of the Mechanism of Ethyleneglycol Monoacetate Formation in Oxidative Acetoxylation of Ethylene Catalyzed by Pd(II) Complexes
В сборнике New Developments in Selective Oxidation : Proceedings of an International Symposium, Rimini, Italy, September 18-22, 1989. 1990. – C.213-220. – ISBN 9780444886941. DOI: 10.1016/S0167-2991(08)60151-2 WOS Scopus РИНЦ CAPlusCA OpenAlex
1H NMR Study of the Mechanism of Ethyleneglycol Monoacetate Formation in Oxidative Acetoxylation of Ethylene Catalyzed by Pd(II) Complexes
В сборнике New Developments in Selective Oxidation : Proceedings of an International Symposium, Rimini, Italy, September 18-22, 1989. 1990. – C.213-220. – ISBN 9780444886941. DOI: 10.1016/S0167-2991(08)60151-2 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Опубликована в печати: | 1 янв. 1990 г. |
| Опубликована online: | 4 мар. 2008 г. |
Идентификаторы БД:
| Web of science: | WOS:A1990BQ92M00022 |
| Scopus: | 2-s2.0-77956928035 |
| РИНЦ: | 30705829 |
| Chemical Abstracts: | 2010:1601960 |
| Chemical Abstracts (print): | 156:420900 |
| OpenAlex: | W168797892 |