1H NMR Study of the Mechanism of Ethyleneglycol Monoacetate Formation in Oxidative Acetoxylation of Ethylene Catalyzed by Pd(II) Complexes Full article
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New Developments in Selective Oxidation: International Symposium 18-22 Sep 1989 , Rimini |
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| Source | New Developments in Selective Oxidation : Proceedings of an International Symposium, Rimini, Italy, September 18-22, 1989 Compilation, 1990. 891 c. ISBN 9780444886941. |
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| Journal |
Studies in Surface Science and Catalysis
ISSN: 0167-2991 |
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| Output data | Year: 1990, Volume: 55, Pages: 213-220 Pages count : 8 DOI: 10.1016/S0167-2991(08)60151-2 | ||
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Abstract:
A detailed mechanism of ethylene oxidation by Pd(NOn)CIL2 complexes (n=2,3; L=CD3CN) in a chloroform-acetic acid nmixture is studied by 1H N M R spectroscopy. The end reaction products are ethyleneglycol monoacetate (EGMA), acetaldehyde, nitroethylene and compounds with the general formula CH3-CHXY (X, Y = OH, OAc, Cl, NO2), whose ratio depends upon the solvent composition. Kinetic and spectral data obtained indicate the formation of a number of intermediates. The structure and routes of decomposition of the intermediates to EGMA and other reaction products are suggested.
Cite:
Gusevskaya E.V.
, Beck I.E.
, Stepanov A.G.
, Likholobov V.A.
, Zamaraev K.I.
1H NMR Study of the Mechanism of Ethyleneglycol Monoacetate Formation in Oxidative Acetoxylation of Ethylene Catalyzed by Pd(II) Complexes
In compilation New Developments in Selective Oxidation : Proceedings of an International Symposium, Rimini, Italy, September 18-22, 1989. 1990. – C.213-220. – ISBN 9780444886941. DOI: 10.1016/S0167-2991(08)60151-2 WOS Scopus РИНЦ ANCAN OpenAlex
1H NMR Study of the Mechanism of Ethyleneglycol Monoacetate Formation in Oxidative Acetoxylation of Ethylene Catalyzed by Pd(II) Complexes
In compilation New Developments in Selective Oxidation : Proceedings of an International Symposium, Rimini, Italy, September 18-22, 1989. 1990. – C.213-220. – ISBN 9780444886941. DOI: 10.1016/S0167-2991(08)60151-2 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Published print: | Jan 1, 1990 |
| Published online: | Mar 4, 2008 |
Identifiers:
| Web of science: | WOS:A1990BQ92M00022 |
| Scopus: | 2-s2.0-77956928035 |
| Elibrary: | 30705829 |
| Chemical Abstracts: | 2010:1601960 |
| Chemical Abstracts (print): | 156:420900 |
| OpenAlex: | W168797892 |