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Lattice-Gas Model for Description of the Adsorbed Molecules of Two Kinds Научная публикация

Журнал Surface Science
ISSN: 0039-6028
Вых. Данные Год: 1981, Том: 111, Номер: 1, Страницы: 63-79 Страниц : 17 DOI: 10.1016/0039-6028(81)90475-1
Авторы Zhdanov V.P. 1
Организации
1 Institute of Catalysis, Novosibirsk 630090, USSR

Реферат: Using the absolute rate theory, some general formulas are derived for description of the effect of the lateral interactions of adsorbed molecules of two kinds on the rate constants of monomolecular desorption and adsorption, associative desorption and dissociative adsorption, the Eley-Rideal and Langmuir-Hinshelwood reactions. The rate constants of these processes are expressed through the probabilities of distribution of particles on surface, calculated in the quasi-chemical approximation. Numerical calculation of dependence on the rate constants of desorption and the Langmuir-Hinshelwood reaction on surface coverages are presented. Different approximations used earlier for description of the influence of the lateral interaction on the rate of desorption are compared. The influence of ordering of adsorbed molecules on the precursor state kinetics of monomolecular adsorption and desorption is considered.
Библиографическая ссылка: Zhdanov V.P.
Lattice-Gas Model for Description of the Adsorbed Molecules of Two Kinds
Surface Science. 1981. V.111. N1. P.63-79. DOI: 10.1016/0039-6028(81)90475-1 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 11 февр. 1981 г.
Принята к публикации: 27 мая 1981 г.
Опубликована в печати: 2 окт. 1981 г.
Опубликована online: 23 сент. 2002 г.
Идентификаторы БД:
Web of science: WOS:A1981MP57000014
Scopus: 2-s2.0-0002894104
РИНЦ: 30856829
Chemical Abstracts: 1981:610249
Chemical Abstracts (print): 95:210249
OpenAlex: W2020069902
Цитирование в БД:
БД Цитирований
Web of science 113
Scopus 106
РИНЦ 101
OpenAlex 116
Альметрики: