Autocatalytic Dehydrogenation of Propane | Sciact - CRIS-система Института катализа

Autocatalytic Dehydrogenation of Propane Научная публикация

Конференция

OPU-KIST-ECUST Joint Symposium on Advanced Materials and their Applications
10-10 сент. 2012 , Sakai

Журнал

Research on Chemical Intermediates
ISSN: 0922-6168 , E-ISSN: 1568-5675

Вых. Данные

Год: 2014, Том: 40, Номер: 1, Страницы: 345-356 Страниц : 12 DOI: 10.1007/s11164-012-0967-1

Ключевые слова

Autocatalysis, Ethylene biradical, Laser irradiation, Propane pyrolysis

Авторы

Snytnikov V.N. ^1,2 , Mishchenko T.I. ^1,2 , Snytnikov Vl.N. ^1,2 , Chernykh I.G. ³

Организации

1	Boreskov Institute of Catalysis, Lavrentieva 5, Novosibirsk, Russia
2	UNICAT Ltd, Lavrentieva 5, Novosibirsk 630090, Russia
3	Institute of Computational Mathematics and Mathematical Geophysics, Lavrentieva 6, Novosibirsk, Russia

Информация о финансировании (4)

1	Российский фонд фундаментальных исследований	12-07-00065
2	Российский фонд фундаментальных исследований	12-08-00871
3	Фонд «Сколково»	130
4	Совет по грантам Президента Российской Федерации	НШ-524.2012.3

Homogeneous gas-phase pyrolysis of propane was performed by using continuous CO2 laser irradiation for bulk heating of the reaction mixture. Laser energy was absorbed by ethylene, the main product of propane dehydrogenation, and transferred to the reaction medium via collisional relaxation. A mechanism of propane dehydrogenation is suggested to describe the pyrolysis process. The mechanism involves autocatalysis by ethylene and includes propane–ethylene interaction with the formation of ethyl and propyl radicals.

Snytnikov V.N. , Mishchenko T.I. , Snytnikov V.N. , Chernykh I.G.
Autocatalytic Dehydrogenation of Propane
Research on Chemical Intermediates. 2014. V.40. N1. P.345-356. DOI: 10.1007/s11164-012-0967-1 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	7 нояб. 2012 г.
Принята к публикации:	3 дек. 2012 г.
Опубликована online:	9 янв. 2013 г.
Опубликована в печати:	1 янв. 2014 г.

Web of science:	WOS:000329795500033
Scopus:	2-s2.0-84892801022
РИНЦ:	23957193
Chemical Abstracts:	2013:56745
Chemical Abstracts (print):	160:88133
OpenAlex:	W2013112687

БД	Цитирований
Web of science	3
Scopus	4
РИНЦ	16
OpenAlex	6