Autocatalytic Dehydrogenation of Propane Full article
| Conference |
OPU-KIST-ECUST Joint Symposium on Advanced Materials and their Applications 10-10 Sep 2012 , Sakai |
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| Journal |
Research on Chemical Intermediates
ISSN: 0922-6168 , E-ISSN: 1568-5675 |
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| Output data | Year: 2014, Volume: 40, Number: 1, Pages: 345-356 Pages count : 12 DOI: 10.1007/s11164-012-0967-1 | ||||||
| Tags | Autocatalysis, Ethylene biradical, Laser irradiation, Propane pyrolysis | ||||||
| Authors |
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| Affiliations |
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Funding (4)
| 1 | Russian Foundation for Basic Research | 12-07-00065 |
| 2 | Russian Foundation for Basic Research | 12-08-00871 |
| 3 | Skolkovo Foundation | 130 |
| 4 | Council for Grants of the President of the Russian Federation | НШ-524.2012.3 |
Abstract:
Homogeneous gas-phase pyrolysis of propane was performed by using continuous CO2 laser irradiation for bulk heating of the reaction mixture. Laser energy was absorbed by ethylene, the main product of propane dehydrogenation, and transferred to the reaction medium via collisional relaxation. A mechanism of propane dehydrogenation is suggested to describe the pyrolysis process. The mechanism involves autocatalysis by ethylene and includes propane–ethylene interaction with the formation of ethyl and propyl radicals.
Cite:
Snytnikov V.N.
, Mishchenko T.I.
, Snytnikov V.N.
, Chernykh I.G.
Autocatalytic Dehydrogenation of Propane
Research on Chemical Intermediates. 2014. V.40. N1. P.345-356. DOI: 10.1007/s11164-012-0967-1 WOS Scopus РИНЦ ANCAN OpenAlex
Autocatalytic Dehydrogenation of Propane
Research on Chemical Intermediates. 2014. V.40. N1. P.345-356. DOI: 10.1007/s11164-012-0967-1 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Nov 7, 2012 |
| Accepted: | Dec 3, 2012 |
| Published online: | Jan 9, 2013 |
| Published print: | Jan 1, 2014 |
Identifiers:
| Web of science: | WOS:000329795500033 |
| Scopus: | 2-s2.0-84892801022 |
| Elibrary: | 23957193 |
| Chemical Abstracts: | 2013:56745 |
| Chemical Abstracts (print): | 160:88133 |
| OpenAlex: | W2013112687 |