Реферат: Among a series of low-oxidation state transition-metal (Mo, W, V, Zr) catalysts on oxide carriers the catalysts containing isolated Mo(II) ions were most active in NH3 synthesis. For the catalyst prepared by a reaction of π-allyl Mo (Mo(C3H5)4) with SiO2 the catalytic activity per Mo atom did not change when the Mo concentration on SiO2 changed from 1017 to 1018 ions/m2 and the NH3-synthesis activation energy was const., ∼25 kcal/mole. The catalytic activity of Mo(II) depended greatly on the oxide-carrier nature. The SiO2, Al2O3, Cr2O3, Fe2O3, and Co3O4 were investigated as the carriers.

Библиографическая ссылка: Kuznetsov B.N. , Kuznetsov V.L. , Ermakov Y.I.
Catalysts Produced by the Interaction of Organometallic Compounds of Transition Metals with Support Surfaces. Synthesis of Ammonia on Supported Molybdenum Catalysts
Kinetics and Catalysis. 1975. V.16. N4. P.790-793. WOS РИНЦ

Оригинальная: Кузнецов Б.Н. , Кузнецов В.Л. , Ермаков Ю.И.
Катализаторы, полученные взаимодействием металлоорганических соединений переходных металлов с поверхностью носителей. Синтез аммиака на нанесенных молибденовых катализаторах
Кинетика и катализ. 1975. Т.16. №4. С.915-918. РИНЦ CAPlusCA

Даты:

Поступила в редакцию:

23 окт. 1973 г.

Идентификаторы БД:

Web of science:	WOS:A1975BP32600017
РИНЦ:	30625187

Цитирование в БД:

БД	Цитирований
Web of science	2