Understanding Methane Aromatization on a Zn-Modified High-Silica Zeolite | Sciact - CRIS-система Института катализа

Understanding Methane Aromatization on a Zn-Modified High-Silica Zeolite Научная публикация

Журнал

Angewandte Chemie - International Edition
ISSN: 1433-7851 , E-ISSN: 1521-3773

Вых. Данные

Год: 2008, Том: 47, Номер: 24, Страницы: 4559-4562 Страниц : 4 DOI: 10.1002/anie.200800317

Ключевые слова

Mass spectrometry, Methane, NMR spectroscopy, Reaction mechanisms, Zeolites

Авторы

Luzgin Mikhail V. ¹ , Rogov Vladimir A. ¹ , Arzumanov Sergei S. ¹ , Toktarev Alexander V. ¹ , Stepanov Alexander G. ¹ , Parmon Valentin N. ¹

Организации

1	Boreskov Institute of Catalysis Siberian Branch of the Russian Academy of Sciences, Prospekt Akademika Lavrentieva 5, Novosibirsk 630090 (Russia)

It takes two: A high level of conversion of 13C atoms of methane into the products of methane/propane coaromatization on zeolite Zn/H-BEA has been demonstrated by 13C solid-state NMR spectroscopic analysis and GC-MS. The isotope-labeling experiments show the mechanism consists of the methylation of aromatic compounds formed from the propane followed by ring-expansion/contraction (see scheme).

Luzgin M.V. , Rogov V.A. , Arzumanov S.S. , Toktarev A.V. , Stepanov A.G. , Parmon V.N.
Understanding Methane Aromatization on a Zn-Modified High-Silica Zeolite
Angewandte Chemie - International Edition. 2008. V.47. N24. P.4559-4562. DOI: 10.1002/anie.200800317 WOS Scopus РИНЦ CAPlusCA PMID OpenAlex OpenAlex

Поступила в редакцию:	22 янв. 2008 г.
Принята к публикации:	22 февр. 2008 г.
Опубликована online:	2 мая 2008 г.
Опубликована в печати:	2 июн. 2008 г.

Web of science:	WOS:000256549900017
Scopus:	2-s2.0-53549134274
РИНЦ:	13581568
Chemical Abstracts:	2008:769476
Chemical Abstracts (print):	149:270815
PMID (PubMed):	18454437
OpenAlex:	W1977878401 \| W4237814150

БД	Цитирований
Web of science	147
Scopus	151
РИНЦ	140
OpenAlex	160 30