Understanding Methane Aromatization on a Zn-Modified High-Silica Zeolite | Sciact - CRIS-system of Boreskov Institute of Catalysis

Understanding Methane Aromatization on a Zn-Modified High-Silica Zeolite Full article

Journal

Angewandte Chemie - International Edition
ISSN: 1433-7851 , E-ISSN: 1521-3773

Output data

Year: 2008, Volume: 47, Number: 24, Pages: 4559-4562 Pages count : 4 DOI: 10.1002/anie.200800317

Tags

Mass spectrometry, Methane, NMR spectroscopy, Reaction mechanisms, Zeolites

Authors

Luzgin Mikhail V. ¹ , Rogov Vladimir A. ¹ , Arzumanov Sergei S. ¹ , Toktarev Alexander V. ¹ , Stepanov Alexander G. ¹ , Parmon Valentin N. ¹

Affiliations

1	Boreskov Institute of Catalysis Siberian Branch of the Russian Academy of Sciences, Prospekt Akademika Lavrentieva 5, Novosibirsk 630090 (Russia)

It takes two: A high level of conversion of 13C atoms of methane into the products of methane/propane coaromatization on zeolite Zn/H-BEA has been demonstrated by 13C solid-state NMR spectroscopic analysis and GC-MS. The isotope-labeling experiments show the mechanism consists of the methylation of aromatic compounds formed from the propane followed by ring-expansion/contraction (see scheme).

Luzgin M.V. , Rogov V.A. , Arzumanov S.S. , Toktarev A.V. , Stepanov A.G. , Parmon V.N.
Understanding Methane Aromatization on a Zn-Modified High-Silica Zeolite
Angewandte Chemie - International Edition. 2008. V.47. N24. P.4559-4562. DOI: 10.1002/anie.200800317 WOS Scopus РИНЦ ANCAN PMID OpenAlex OpenAlex

Submitted:	Jan 22, 2008
Accepted:	Feb 22, 2008
Published online:	May 2, 2008
Published print:	Jun 2, 2008

Web of science:	WOS:000256549900017
Scopus:	2-s2.0-53549134274
Elibrary:	13581568
Chemical Abstracts:	2008:769476
Chemical Abstracts (print):	149:270815
PMID:	18454437
OpenAlex:	W1977878401 \| W4237814150

DB	Citing
Web of science	147
Scopus	151
Elibrary	140
OpenAlex	160 30