Kinetic Behavior of Benzene Hydrogenation and Thiophene Hydrogenolysis on Sulfide Ni-Mo/Al2O3 Catalyst Научная публикация
| Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Вых. Данные | Год: 2006, Том: 88, Номер: 2, Страницы: 325-332 Страниц : 8 DOI: 10.1007/s11144-006-0068-5 | ||
| Ключевые слова | Benzene hydrogenation, Sulfide catalyst, Transient kinetics | ||
| Авторы |
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| Организации |
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Реферат:
An unsteady-state kinetic model of both benzene hydrogenation (HDA) and thiophene hydrogenolysis (HDS) on a sulfide hydrotreating catalyst Ni-Mo/Al2O3 has been developed. The model adequately describes experimental data obtained at the pressure 2 MPa, temperature 573 K and at various contact times and ratios of benzene/thiophene. The model is based on the assumption that the catalyst surface contains only one type of active sites, i.e., Ni atoms in the sulfide bimetallic species, which are responsible for both hydrogenolysis and hydrogenation reactions.
Библиографическая ссылка:
Ivanov E.A.
, Reshetnikov S.I.
, Sidyakin M.V.
, Startsev A.N.
Kinetic Behavior of Benzene Hydrogenation and Thiophene Hydrogenolysis on Sulfide Ni-Mo/Al2O3 Catalyst
Reaction Kinetics and Catalysis Letters. 2006. V.88. N2. P.325-332. DOI: 10.1007/s11144-006-0068-5 WOS Scopus РИНЦ CAPlusCA OpenAlex
Kinetic Behavior of Benzene Hydrogenation and Thiophene Hydrogenolysis on Sulfide Ni-Mo/Al2O3 Catalyst
Reaction Kinetics and Catalysis Letters. 2006. V.88. N2. P.325-332. DOI: 10.1007/s11144-006-0068-5 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 6 мар. 2006 г. |
| Принята к публикации: | 20 мар. 2006 г. |
| Опубликована в печати: | 1 авг. 2006 г. |
Идентификаторы БД:
| Web of science: | WOS:000239050100016 |
| Scopus: | 2-s2.0-33746096168 |
| РИНЦ: | 13513684 |
| Chemical Abstracts: | 2006:924573 |
| Chemical Abstracts (print): | 146:84243 |
| OpenAlex: | W2028557355 |