Kinetic Behavior of Benzene Hydrogenation and Thiophene Hydrogenolysis on Sulfide Ni-Mo/Al2O3 Catalyst Full article
| Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Output data | Year: 2006, Volume: 88, Number: 2, Pages: 325-332 Pages count : 8 DOI: 10.1007/s11144-006-0068-5 | ||
| Tags | Benzene hydrogenation, Sulfide catalyst, Transient kinetics | ||
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Abstract:
An unsteady-state kinetic model of both benzene hydrogenation (HDA) and thiophene hydrogenolysis (HDS) on a sulfide hydrotreating catalyst Ni-Mo/Al2O3 has been developed. The model adequately describes experimental data obtained at the pressure 2 MPa, temperature 573 K and at various contact times and ratios of benzene/thiophene. The model is based on the assumption that the catalyst surface contains only one type of active sites, i.e., Ni atoms in the sulfide bimetallic species, which are responsible for both hydrogenolysis and hydrogenation reactions.
Cite:
Ivanov E.A.
, Reshetnikov S.I.
, Sidyakin M.V.
, Startsev A.N.
Kinetic Behavior of Benzene Hydrogenation and Thiophene Hydrogenolysis on Sulfide Ni-Mo/Al2O3 Catalyst
Reaction Kinetics and Catalysis Letters. 2006. V.88. N2. P.325-332. DOI: 10.1007/s11144-006-0068-5 WOS Scopus РИНЦ ANCAN OpenAlex
Kinetic Behavior of Benzene Hydrogenation and Thiophene Hydrogenolysis on Sulfide Ni-Mo/Al2O3 Catalyst
Reaction Kinetics and Catalysis Letters. 2006. V.88. N2. P.325-332. DOI: 10.1007/s11144-006-0068-5 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Mar 6, 2006 |
| Accepted: | Mar 20, 2006 |
| Published print: | Aug 1, 2006 |
Identifiers:
| Web of science: | WOS:000239050100016 |
| Scopus: | 2-s2.0-33746096168 |
| Elibrary: | 13513684 |
| Chemical Abstracts: | 2006:924573 |
| Chemical Abstracts (print): | 146:84243 |
| OpenAlex: | W2028557355 |