Fe(II) Complex with Chiral Pyrazolylquinoline L and Fe(II), Co(II), and Cu(II) Complexes with Achiral Pyrazolylquinoline L1 : Synthesis and Properties. The Crystal Structures of [ML1Cl2] (M = Fe, Co, and Cu) | Sciact - CRIS-система Института катализа

Fe(II) Complex with Chiral Pyrazolylquinoline L and Fe(II), Co(II), and Cu(II) Complexes with Achiral Pyrazolylquinoline L1 : Synthesis and Properties. The Crystal Structures of [ML1Cl2] (M = Fe, Co, and Cu) Научная публикация

Журнал

Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318

Вых. Данные

Год: 2008, Том: 34, Номер: 4, Страницы: 278-285 Страниц : 8 DOI: 10.1134/S1070328408040076

Ключевые слова

Coordination Chemistry; Ethylene Polymerization; Vacuum Suction; Short Intermolecular Contact; Nonmetal Atom

Авторы

Savelʹeva Z.A. ¹ , Glinskaya L.A. ¹ , Klevtsova R.F. ¹ , Popov S.A. ² , Tkachev A.V. ² , Semikolenova N.V. ³ , Zakharov V.A. ³ , Larionov S.V. ¹

Организации

1	Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090 Russia
2	Vorozhtsov Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia
3	Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090 Russia

The complexes FeLCl2 (I), [FeL1Cl2] (II), [CoL1Cl2] (III), and [CuL1Cl2] (IV) (where L and L1 are chiral and achiral pyrazolylquinolines, respectively) were obtained. Complexes II–IV were structurally characterized by single-crystal X-ray diffraction analysis. Crystals of complexes II and III are triclinic (space group P ) and crystals of complex IV are monoclinic (space group P21/n). Structures II–IV are built from discrete mononuclear acentric molecules. In these complexes, the M2+ ion (M = Fe, Co, and Cu) coordinates two N atoms of the bidentate chelating ligand L1 and two Cl atoms. The coordination cores MCl2N2 are distorted tetrahedra. For complexes I and II, µeff = 5.05 and 5.07 µB, respectively, correspond to the high-spin configuration d6. For complex III, µeff = 4.51 µB (high-spin configuration d7) and for complex IV, µeff = 1.80 µB (configuration d9).

Savelʹeva Z.A. , Glinskaya L.A. , Klevtsova R.F. , Popov S.A. , Tkachev A.V. , Semikolenova N.V. , Zakharov V.A. , Larionov S.V.
Fe(II) Complex with Chiral Pyrazolylquinoline L and Fe(II), Co(II), and Cu(II) Complexes with Achiral Pyrazolylquinoline L1 : Synthesis and Properties. The Crystal Structures of [ML1Cl2] (M = Fe, Co, and Cu)
Russian Journal of Coordination Chemistry. 2008. V.34. N4. P.278-285. DOI: 10.1134/S1070328408040076 WOS Scopus РИНЦ CAPlusCA OpenAlex

Савельева З.А. , Глинская Л.А. , Клевцова Р.Ф. , Попов С.А. , Ткачев А.В. , Семиколенова Н.В. , Захаров В.А. , Ларионов С.В.
Синтез и свойства комплекса Fe(II) с хиральным пиразолилхинолином L и комплексов Fe(II), Co(II), Cu(II) с ахиральным пиразолилхинолином L1. Кристаллическая структура соединений [ML1Cl2] (M = Fe, Co, Cu)
Координационная химия. 2008. Т.34. №4. С.285-292. РИНЦ

Поступила в редакцию:	16 апр. 2007 г.
Опубликована в печати:	1 апр. 2008 г.
Опубликована online:	4 мая 2008 г.

Web of science:	WOS:000255586800007
Scopus:	2-s2.0-43249130508
РИНЦ:	13566398
Chemical Abstracts:	2008:535732
Chemical Abstracts (print):	150:529563
OpenAlex:	W2047761127

БД	Цитирований
Web of science	2
Scopus	2
РИНЦ	1
OpenAlex	3