Fe(II) Complex with Chiral Pyrazolylquinoline L and Fe(II), Co(II), and Cu(II) Complexes with Achiral Pyrazolylquinoline L1 : Synthesis and Properties. The Crystal Structures of [ML1Cl2] (M = Fe, Co, and Cu) Full article
| Journal |
Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318 |
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| Output data | Year: 2008, Volume: 34, Number: 4, Pages: 278-285 Pages count : 8 DOI: 10.1134/S1070328408040076 | ||||||
| Tags | Coordination Chemistry; Ethylene Polymerization; Vacuum Suction; Short Intermolecular Contact; Nonmetal Atom | ||||||
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Abstract:
The complexes FeLCl2 (I), [FeL1Cl2] (II), [CoL1Cl2] (III), and [CuL1Cl2] (IV) (where L and L1 are chiral
and achiral pyrazolylquinolines, respectively) were obtained. Complexes II–IV were structurally characterized by
single-crystal X-ray diffraction analysis. Crystals of complexes II and III are triclinic (space group P ) and crystals
of complex IV are monoclinic (space group P21/n). Structures II–IV are built from discrete mononuclear acentric
molecules. In these complexes, the M2+ ion (M = Fe, Co, and Cu) coordinates two N atoms of the bidentate chelating
ligand L1 and two Cl atoms. The coordination cores MCl2N2 are distorted tetrahedra. For complexes I and II,
µeff = 5.05 and 5.07 µB, respectively, correspond to the high-spin configuration d6. For complex III, µeff = 4.51 µB
(high-spin configuration d7) and for complex IV, µeff = 1.80 µB (configuration d9).
Cite:
Savelʹeva Z.A.
, Glinskaya L.A.
, Klevtsova R.F.
, Popov S.A.
, Tkachev A.V.
, Semikolenova N.V.
, Zakharov V.A.
, Larionov S.V.
Fe(II) Complex with Chiral Pyrazolylquinoline L and Fe(II), Co(II), and Cu(II) Complexes with Achiral Pyrazolylquinoline L1 : Synthesis and Properties. The Crystal Structures of [ML1Cl2] (M = Fe, Co, and Cu)
Russian Journal of Coordination Chemistry. 2008. V.34. N4. P.278-285. DOI: 10.1134/S1070328408040076 WOS Scopus РИНЦ ANCAN OpenAlex
Fe(II) Complex with Chiral Pyrazolylquinoline L and Fe(II), Co(II), and Cu(II) Complexes with Achiral Pyrazolylquinoline L1 : Synthesis and Properties. The Crystal Structures of [ML1Cl2] (M = Fe, Co, and Cu)
Russian Journal of Coordination Chemistry. 2008. V.34. N4. P.278-285. DOI: 10.1134/S1070328408040076 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Савельева З.А.
, Глинская Л.А.
, Клевцова Р.Ф.
, Попов С.А.
, Ткачев А.В.
, Семиколенова Н.В.
, Захаров В.А.
, Ларионов С.В.
Синтез и свойства комплекса Fe(II) с хиральным пиразолилхинолином L и комплексов Fe(II), Co(II), Cu(II) с ахиральным пиразолилхинолином L1. Кристаллическая структура соединений [ML1Cl2] (M = Fe, Co, Cu)
Координационная химия. 2008. Т.34. №4. С.285-292. РИНЦ
Синтез и свойства комплекса Fe(II) с хиральным пиразолилхинолином L и комплексов Fe(II), Co(II), Cu(II) с ахиральным пиразолилхинолином L1. Кристаллическая структура соединений [ML1Cl2] (M = Fe, Co, Cu)
Координационная химия. 2008. Т.34. №4. С.285-292. РИНЦ
Dates:
| Submitted: | Apr 16, 2007 |
| Published print: | Apr 1, 2008 |
| Published online: | May 4, 2008 |
Identifiers:
| Web of science: | WOS:000255586800007 |
| Scopus: | 2-s2.0-43249130508 |
| Elibrary: | 13566398 |
| Chemical Abstracts: | 2008:535732 |
| Chemical Abstracts (print): | 150:529563 |
| OpenAlex: | W2047761127 |