129Xe NMR Spectroscopy of Adsorbed Xenon: Possibilites for Exploration of Microporous Carbon Materials | Sciact - CRIS-система Института катализа

129Xe NMR Spectroscopy of Adsorbed Xenon: Possibilites for Exploration of Microporous Carbon Materials Научная публикация

Журнал

Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350

Вых. Данные

Год: 2008, Том: 78, Номер: 11, Страницы: 2171-2181 Страниц : 11 DOI: 10.1134/S1070363208110388

Ключевые слова

Zeolite; Chemical Shift; Activate Carbon; Xenon; General Chemistry

Авторы

Romanenko K.V. ¹ , Lapina O.B. ¹ , Py X. ² , Fraissard J. ³

Организации

1	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. Lavrent’eva 5, Novosibirsk, 630090 Russia
2	CNRS-PROMES, Processes Materials and Solar Energy Laboratory, Rambla de la Thermodynamique, Tecnosud, 66100 Perpignan Cedex, France
3	Laboratoire de Physique Quantique, UMR CNRS 7142,Ecole Supérieure de Physique et de Chimie Industrielles (ESPCI), 75231 Paris Cedex 05, France

Информация о финансировании (1)

Посольство Франции в России

Despite the extensive use of 129Xe NMR for characterization of high surface-to-volume porous solids, particularly zeolites, this method has not been widely used to explore the properties of microporous carbon materials. In this study, commercial amorphous carbons of different origin (produced from different precursors) and a series of activated carbons obtained by successive cyclic air oxidation/pyrolysis treatments of a single precursor were examined. Models of 129Xe chemical shift as a function of local Xe density, mean pore size, and temperature are discussed. The virial coefficient arising from binary xenon collisions, δXe–Xe, varied linearly with the mean pore size given by N2 adsorption analysis; δXe–Xe appeared to be a better probe of the mean pore size than the chemical shift extrapolated to zero pressure, δS.

Romanenko K.V. , Lapina O.B. , Py X. , Fraissard J.
129Xe NMR Spectroscopy of Adsorbed Xenon: Possibilites for Exploration of Microporous Carbon Materials
Russian Journal of General Chemistry. 2008. V.78. N11. P.2171-2181. DOI: 10.1134/S1070363208110388 WOS Scopus РИНЦ CAPlusCA OpenAlex

Романенко К.В. , Лапина О.Б. , Пи К. , Фрессар Ж.
Спектроскопия 129Хе ЯМР адсорбированного ксенона: возможности в исследовании микропористых углеродных материалов
Российский химический журнал. 2008. Т.52. №1. С.3-12. РИНЦ CAPlusCA

Поступила в редакцию:	10 сент. 2007 г.
Опубликована в печати:	1 нояб. 2008 г.
Опубликована online:	23 дек. 2008 г.

Web of science:	WOS:000261959400038
Scopus:	2-s2.0-59849124659
РИНЦ:	13580266
Chemical Abstracts:	2008:1523866
Chemical Abstracts (print):	152:248222
OpenAlex:	W1997741854

БД	Цитирований
Web of science	5
Scopus	5
РИНЦ	4
OpenAlex	5