129Xe NMR Spectroscopy of Adsorbed Xenon: Possibilites for Exploration of Microporous Carbon Materials Full article
| Journal |
Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350 |
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| Output data | Year: 2008, Volume: 78, Number: 11, Pages: 2171-2181 Pages count : 11 DOI: 10.1134/S1070363208110388 | ||||||
| Tags | Zeolite; Chemical Shift; Activate Carbon; Xenon; General Chemistry | ||||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | French Embassy in Moscow |
Abstract:
Despite the extensive use of 129Xe NMR for characterization of high surface-to-volume porous
solids, particularly zeolites, this method has not been widely used to explore the properties of microporous
carbon materials. In this study, commercial amorphous carbons of different origin (produced from different
precursors) and a series of activated carbons obtained by successive cyclic air oxidation/pyrolysis treatments of
a single precursor were examined. Models of 129Xe chemical shift as a function of local Xe density, mean pore
size, and temperature are discussed. The virial coefficient arising from binary xenon collisions, δXe–Xe, varied
linearly with the mean pore size given by N2 adsorption analysis; δXe–Xe appeared to be a better probe of the
mean pore size than the chemical shift extrapolated to zero pressure, δS.
Cite:
Romanenko K.V.
, Lapina O.B.
, Py X.
, Fraissard J.
129Xe NMR Spectroscopy of Adsorbed Xenon: Possibilites for Exploration of Microporous Carbon Materials
Russian Journal of General Chemistry. 2008. V.78. N11. P.2171-2181. DOI: 10.1134/S1070363208110388 WOS Scopus РИНЦ ANCAN OpenAlex
129Xe NMR Spectroscopy of Adsorbed Xenon: Possibilites for Exploration of Microporous Carbon Materials
Russian Journal of General Chemistry. 2008. V.78. N11. P.2171-2181. DOI: 10.1134/S1070363208110388 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Романенко К.В.
, Лапина О.Б.
, Пи К.
, Фрессар Ж.
Спектроскопия 129Хе ЯМР адсорбированного ксенона: возможности в исследовании микропористых углеродных материалов
Российский химический журнал. 2008. Т.52. №1. С.3-12. РИНЦ ANCAN
Спектроскопия 129Хе ЯМР адсорбированного ксенона: возможности в исследовании микропористых углеродных материалов
Российский химический журнал. 2008. Т.52. №1. С.3-12. РИНЦ ANCAN
Dates:
| Submitted: | Sep 10, 2007 |
| Published print: | Nov 1, 2008 |
| Published online: | Dec 23, 2008 |
Identifiers:
| Web of science: | WOS:000261959400038 |
| Scopus: | 2-s2.0-59849124659 |
| Elibrary: | 13580266 |
| Chemical Abstracts: | 2008:1523866 |
| Chemical Abstracts (print): | 152:248222 |
| OpenAlex: | W1997741854 |