Sciact
  • EN
  • RU

Electrodeposited Non-Stoichiometric Tungstic Acid for Electrochromic Applications: Film Growth Modes, Crystal Structure, Redox Behavior and Stability Full article

Conference 2015 E-MRS Fall Meeting. 12th International Symposium D - Electrochemical/Chemical Reactivity of New Materials
15-18 Sep 2015 , Warsaw
Journal Applied Surface Science
ISSN: 0169-4332
Output data Year: 2016, Volume: 388, Number: Part B, Pages: 786-793 Pages count : 8 DOI: 10.1016/j.apsusc.2016.04.168
Tags Electrochromic films, Non-stoichiometry, Oxide electrodeposition, Tungstic acid
Authors Pugovkin Leonid V. 1 , Sherstyuk Olga V. 2,3 , Plyasova Lyudmila M. 2 , Molina Irina Yu. 2 , Kardash Tatyana Yu. 2,3 , Stonkus Olga A. 2,3 , Yatsenko Dmitriy A. 2,3 , Kaichev Vasily V. 2,3 , Tsirlina Galina A. 1
Affiliations
1 Dept of Electrochemistry, Moscow State University, Russia
2 Boreskov Institute of Catalysis, SB RAS, Novosibirsk, Russia
3 Novosibirsk State University, Novosibirsk, Russia

Funding (2)

1 Federal Agency for Scientific Organizations V.46.4.4.
2 Russian Foundation for Basic Research 14-03-01016

Abstract: Bath composition for cathodic electrodeposition of non-stoichiometric hydrated tungstic acid with high electrochromic efficiency is optimized with account for selective electroreduction of certain isopolytungstates. XRD data for thin electrodeposited films and chemically synthesized bulk tungstic acid dihydrate are compared in the context of reversible oxidation and reduction in hydrogen atmosphere, in presence of Pt catalyst. XPS and ТЕМ techniques are attracted to understand the nature of reversible and less reversible transformations of films in the course of their storage and operation.
Cite: Pugovkin L.V. , Sherstyuk O.V. , Plyasova L.M. , Molina I.Y. , Kardash T.Y. , Stonkus O.A. , Yatsenko D.A. , Kaichev V.V. , Tsirlina G.A.
Electrodeposited Non-Stoichiometric Tungstic Acid for Electrochromic Applications: Film Growth Modes, Crystal Structure, Redox Behavior and Stability
Applied Surface Science. 2016. V.388. NPart B. P.786-793. DOI: 10.1016/j.apsusc.2016.04.168 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Jan 15, 2016
Accepted: Apr 25, 2016
Published online: Apr 27, 2016
Published print: Dec 1, 2016
Identifiers:
Web of science: WOS:000384573600025
Scopus: 2-s2.0-84975143285
Elibrary: 29466868
Chemical Abstracts: 2016:730232
Chemical Abstracts (print): 165:400374
OpenAlex: W2342556159
Citing:
DB Citing
Web of science 10
Scopus 10
Elibrary 13
OpenAlex 10
Altmetrics: