Electrodeposited Non-Stoichiometric Tungstic Acid for Electrochromic Applications: Film Growth Modes, Crystal Structure, Redox Behavior and Stability Full article
| Conference |
2015 E-MRS Fall Meeting. 12th International Symposium D - Electrochemical/Chemical Reactivity of New Materials 15-18 Sep 2015 , Warsaw |
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| Journal |
Applied Surface Science
ISSN: 0169-4332 |
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| Output data | Year: 2016, Volume: 388, Number: Part B, Pages: 786-793 Pages count : 8 DOI: 10.1016/j.apsusc.2016.04.168 | ||||||
| Tags | Electrochromic films, Non-stoichiometry, Oxide electrodeposition, Tungstic acid | ||||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Foundation for Basic Research | 14-03-01016 |
| 2 | Federal Agency for Scientific Organizations | V.46.4.4. |
Abstract:
Bath composition for cathodic electrodeposition of non-stoichiometric hydrated tungstic acid with high electrochromic efficiency is optimized with account for selective electroreduction of certain isopolytungstates. XRD data for thin electrodeposited films and chemically synthesized bulk tungstic acid dihydrate are compared in the context of reversible oxidation and reduction in hydrogen atmosphere, in presence of Pt catalyst. XPS and ТЕМ techniques are attracted to understand the nature of reversible and less reversible transformations of films in the course of their storage and operation.
Cite:
Pugovkin L.V.
, Sherstyuk O.V.
, Plyasova L.M.
, Molina I.Y.
, Kardash T.Y.
, Stonkus O.A.
, Yatsenko D.A.
, Kaichev V.V.
, Tsirlina G.A.
Electrodeposited Non-Stoichiometric Tungstic Acid for Electrochromic Applications: Film Growth Modes, Crystal Structure, Redox Behavior and Stability
Applied Surface Science. 2016. V.388. NPart B. P.786-793. DOI: 10.1016/j.apsusc.2016.04.168 WOS Scopus РИНЦ OpenAlex ANCAN
Electrodeposited Non-Stoichiometric Tungstic Acid for Electrochromic Applications: Film Growth Modes, Crystal Structure, Redox Behavior and Stability
Applied Surface Science. 2016. V.388. NPart B. P.786-793. DOI: 10.1016/j.apsusc.2016.04.168 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Submitted: | Jan 15, 2016 |
| Accepted: | Apr 25, 2016 |
| Published online: | Apr 27, 2016 |
| Published print: | Dec 1, 2016 |
Identifiers:
| ≡ Web of science: | WOS:000384573600025 |
| ≡ Scopus: | 2-s2.0-84975143285 |
| ≡ Elibrary: | 29466868 |
| ≡ OpenAlex: | W2342556159 |
| ≡ Chemical Abstracts: | 2016:730232 |
| ≡ Chemical Abstracts (print): | 165:400374 |