Aqueous-Alkaline NaBH4 Solutions: The Influence of Hydride Decomposition on Catalytic Properties of Co3O4 Научная публикация
| Журнал |
Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905 |
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| Вых. Данные | Год: 2016, Том: 85, Страницы: 9-12 Страниц : 4 DOI: 10.1016/j.catcom.2016.07.004 | ||||
| Ключевые слова | Catalyst, Cobalt, Hydrolysis, Reduction, Sodium borohydride | ||||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Федеральное агентство научных организаций России | V.49.1.6. |
Реферат:
The formation of the catalytically active phase of cobalt catalysts from Co3O4 has been studied in fresh aqueous-alkaline NaBH4 solution and in solution after 1 year of storage. It was noted that the hydride concentration of the aged solution was reduced from 15 to 5.1 wt% while its pH increased from 11.5 to 12.9 with the formation of sodium borates. It was these changes in the solution composition that were responsible for the longer time of activation of the cobalt catalyst and its low activity for NaBH4 hydrolysis as compared with the catalyst that was reduced in the fresh solution.
Библиографическая ссылка:
Netskina O.V.
, Komova O.V.
, Mukha S.A.
, Simagina V.I.
Aqueous-Alkaline NaBH4 Solutions: The Influence of Hydride Decomposition on Catalytic Properties of Co3O4
Catalysis Communications. 2016. V.85. P.9-12. DOI: 10.1016/j.catcom.2016.07.004 WOS Scopus РИНЦ OpenAlex CAPlusCA
Aqueous-Alkaline NaBH4 Solutions: The Influence of Hydride Decomposition on Catalytic Properties of Co3O4
Catalysis Communications. 2016. V.85. P.9-12. DOI: 10.1016/j.catcom.2016.07.004 WOS Scopus РИНЦ OpenAlex CAPlusCA
Даты:
| Поступила в редакцию: | 20 апр. 2016 г. |
| Принята к публикации: | 7 июл. 2016 г. |
| Опубликована online: | 8 июл. 2016 г. |
| Опубликована в печати: | 5 окт. 2016 г. |
Идентификаторы БД:
| ≡ Web of science: | WOS:000382594800003 |
| ≡ Scopus: | 2-s2.0-84978245846 |
| ≡ РИНЦ: | 27018605 |
| ≡ OpenAlex: | W2473620666 |
| ≡ Chemical Abstracts: | 2016:1202453 |
| ≡ Chemical Abstracts (print): | 165:372597 |