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Aqueous-Alkaline NaBH4 Solutions: The Influence of Hydride Decomposition on Catalytic Properties of Co3O4 Научная публикация

Журнал Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905
Вых. Данные Год: 2016, Том: 85, Страницы: 9-12 Страниц : 4 DOI: 10.1016/j.catcom.2016.07.004
Ключевые слова Catalyst, Cobalt, Hydrolysis, Reduction, Sodium borohydride
Авторы Netskina O.V. 1,2 , Komova O.V. 1 , Mukha S.A. 1 , Simagina V.I. 1
Организации
1 Laboratory of Hydride Investigation, Boreskov Institute of Catalysis SB RAS, Pr. Akademika Lavrentieva 5, Novosibirsk 630090, Russia
2 Novosibirsk State University, Pirogova Str. 2, Novosibirsk 630090, Russia

Информация о финансировании (1)

1 Федеральное агентство научных организаций России V.49.1.6.

Реферат: The formation of the catalytically active phase of cobalt catalysts from Co3O4 has been studied in fresh aqueous-alkaline NaBH4 solution and in solution after 1 year of storage. It was noted that the hydride concentration of the aged solution was reduced from 15 to 5.1 wt% while its pH increased from 11.5 to 12.9 with the formation of sodium borates. It was these changes in the solution composition that were responsible for the longer time of activation of the cobalt catalyst and its low activity for NaBH4 hydrolysis as compared with the catalyst that was reduced in the fresh solution.
Библиографическая ссылка: Netskina O.V. , Komova O.V. , Mukha S.A. , Simagina V.I.
Aqueous-Alkaline NaBH4 Solutions: The Influence of Hydride Decomposition on Catalytic Properties of Co3O4
Catalysis Communications. 2016. V.85. P.9-12. DOI: 10.1016/j.catcom.2016.07.004 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 20 апр. 2016 г.
Принята к публикации: 7 июл. 2016 г.
Опубликована online: 8 июл. 2016 г.
Опубликована в печати: 5 окт. 2016 г.
Идентификаторы БД:
Web of science: WOS:000382594800003
Scopus: 2-s2.0-84978245846
РИНЦ: 27018605
Chemical Abstracts: 2016:1202453
Chemical Abstracts (print): 165:372597
OpenAlex: W2473620666
Цитирование в БД:
БД Цитирований
Web of science 16
Scopus 16
РИНЦ 16
OpenAlex 16
Альметрики: