Aqueous-Alkaline NaBH4 Solutions: The Influence of Hydride Decomposition on Catalytic Properties of Co3O4 Full article
| Journal |
Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905 |
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| Output data | Year: 2016, Volume: 85, Pages: 9-12 Pages count : 4 DOI: 10.1016/j.catcom.2016.07.004 | ||||
| Tags | Catalyst, Cobalt, Hydrolysis, Reduction, Sodium borohydride | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Federal Agency for Scientific Organizations | V.49.1.6. |
Abstract:
The formation of the catalytically active phase of cobalt catalysts from Co3O4 has been studied in fresh aqueous-alkaline NaBH4 solution and in solution after 1 year of storage. It was noted that the hydride concentration of the aged solution was reduced from 15 to 5.1 wt% while its pH increased from 11.5 to 12.9 with the formation of sodium borates. It was these changes in the solution composition that were responsible for the longer time of activation of the cobalt catalyst and its low activity for NaBH4 hydrolysis as compared with the catalyst that was reduced in the fresh solution.
Cite:
Netskina O.V.
, Komova O.V.
, Mukha S.A.
, Simagina V.I.
Aqueous-Alkaline NaBH4 Solutions: The Influence of Hydride Decomposition on Catalytic Properties of Co3O4
Catalysis Communications. 2016. V.85. P.9-12. DOI: 10.1016/j.catcom.2016.07.004 WOS Scopus РИНЦ OpenAlex ANCAN
Aqueous-Alkaline NaBH4 Solutions: The Influence of Hydride Decomposition on Catalytic Properties of Co3O4
Catalysis Communications. 2016. V.85. P.9-12. DOI: 10.1016/j.catcom.2016.07.004 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Submitted: | Apr 20, 2016 |
| Accepted: | Jul 7, 2016 |
| Published online: | Jul 8, 2016 |
| Published print: | Oct 5, 2016 |
Identifiers:
| ≡ Web of science: | WOS:000382594800003 |
| ≡ Scopus: | 2-s2.0-84978245846 |
| ≡ Elibrary: | 27018605 |
| ≡ OpenAlex: | W2473620666 |
| ≡ Chemical Abstracts: | 2016:1202453 |
| ≡ Chemical Abstracts (print): | 165:372597 |