Реферат: A new catalytic reaction for the single-step synthesis of o-vinylphenol from phenol and acetaldehyde in the gas phase is investigated in this work. A search for an efficient catalyst was made. The best results were obtained with a modified Cr2O3 catalyst supported on γ-Al2O3. The effect of content of Cr2O3 and potassium as a modifying additive was studied. It was shown that the catalyst containing 13% Cr2O3 and 1% K makes it possible to obtain o-vinylphenol with a selectivity of 100% referred to phenol and up to 87% referred to acetaldehyde. The influence of reaction conditions on the activity, selectivity and stability of catalyst operation was elucidated.

Библиографическая ссылка: Parfenov M.V. , Pirutko L.V. , Soshnikov I.E. , Starokon E.V. , Kharitonov A.S. , Panov G.I.
Vinylation of Phenol by Acetaldehyde: A New Reaction for the Synthesis of o-Vinylphenol
Catalysis Communications. 2016. V.86. P.59-62. DOI: 10.1016/j.catcom.2016.08.006 WOS Scopus РИНЦ CAPlusCA OpenAlex

Даты:

Поступила в редакцию:	17 июн. 2016 г.
Принята к публикации:	4 авг. 2016 г.
Опубликована online:	5 авг. 2016 г.
Опубликована в печати:	5 нояб. 2016 г.

Идентификаторы БД:

Web of science:	WOS:000384385900014
Scopus:	2-s2.0-84981501999
РИНЦ:	27135382
Chemical Abstracts:	2016:1341885
Chemical Abstracts (print):	165:300275
OpenAlex:	W2506464307

Цитирование в БД:

БД	Цитирований
Web of science	2
Scopus	2
РИНЦ	2
OpenAlex	2

Альметрики: