Vinylation of Phenol by Acetaldehyde: A New Reaction for the Synthesis of o-Vinylphenol Full article
| Journal |
Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905 |
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| Output data | Year: 2016, Volume: 86, Pages: 59-62 Pages count : 4 DOI: 10.1016/j.catcom.2016.08.006 | ||
| Tags | Acetaldehyde, Monomer, Phenol, Vinylphenol | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Federal Agency for Scientific Organizations | V.44.2.3. |
Abstract:
A new catalytic reaction for the single-step synthesis of o-vinylphenol from phenol and acetaldehyde in the gas phase is investigated in this work. A search for an efficient catalyst was made. The best results were obtained with a modified Cr2O3 catalyst supported on γ-Al2O3. The effect of content of Cr2O3 and potassium as a modifying additive was studied. It was shown that the catalyst containing 13% Cr2O3 and 1% K makes it possible to obtain o-vinylphenol with a selectivity of 100% referred to phenol and up to 87% referred to acetaldehyde. The influence of reaction conditions on the activity, selectivity and stability of catalyst operation was elucidated.
Cite:
Parfenov M.V.
, Pirutko L.V.
, Soshnikov I.E.
, Starokon E.V.
, Kharitonov A.S.
, Panov G.I.
Vinylation of Phenol by Acetaldehyde: A New Reaction for the Synthesis of o-Vinylphenol
Catalysis Communications. 2016. V.86. P.59-62. DOI: 10.1016/j.catcom.2016.08.006 WOS Scopus РИНЦ ANCAN OpenAlex
Vinylation of Phenol by Acetaldehyde: A New Reaction for the Synthesis of o-Vinylphenol
Catalysis Communications. 2016. V.86. P.59-62. DOI: 10.1016/j.catcom.2016.08.006 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Jun 17, 2016 |
| Accepted: | Aug 4, 2016 |
| Published online: | Aug 5, 2016 |
| Published print: | Nov 5, 2016 |
Identifiers:
| Web of science: | WOS:000384385900014 |
| Scopus: | 2-s2.0-84981501999 |
| Elibrary: | 27135382 |
| Chemical Abstracts: | 2016:1341885 |
| Chemical Abstracts (print): | 165:300275 |
| OpenAlex: | W2506464307 |