A Homochiral Metal–Organic Material with Permanent Porosity, Enantioselective Sorption Properties, and Catalytic Activity | Sciact - CRIS-система Института катализа

A Homochiral Metal–Organic Material with Permanent Porosity, Enantioselective Sorption Properties, and Catalytic Activity Научная публикация

Журнал

Angewandte Chemie (German edition)
ISSN: 0044-8249 , E-ISSN: 1521-3757

Вых. Данные

Год: 2006, Том: 118, Номер: 6, Страницы: 930-934 Страниц : 5 DOI: 10.1002/ange.200503023

Ключевые слова

Chirality; Heterogeneous catalysis; Metal-organic frameworks; Microporous materials; Sorption

Авторы

Dybtsev Danil N. ^1,2 , Nuzhdin Alexey L. ³ , Chun Hyungphil ¹ , Bryliakov Konstantin P. ³ , Talsi Evgeniy P. ³ , Fedin Vladimir P. ² , Kim Kimoon ¹

Организации

1	National Creative Research Initiative Center for Smart Supramolecules and Department of Chemistry Division of Molecular and Life Sciences, Pohang University of Science and Technology, San 31 Hyojadong, Pohang 790-784 (Republic of Korea)
2	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Pr. Lavrentieva 3, Novosibirsk 630090 (Russia)
3	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences. Pr. Lavrentieva 5, Novosibirsk 630090 (Russia)

Информация о финансировании (2)

1	Российский фонд фундаментальных исследований	03-03-32009
2	Совет по грантам Президента Российской Федерации	МК-3842.2004.3

A new synthetic approach starting from readily available chemicals successfully produces a robust homochiral metal–organic microporous framework. The material exhibits size- and enantioselective guest-sorption properties (see picture), as well as remarkable catalytic activity with size- and chemoselectivity, and high conversion in the oxidation of thioethers to sulfoxides. Ein neuer Syntheseansatz, der von einfach verfügbaren Chemikalien ausgeht, liefert ein robustes homochirales mikroporöses metall-organisches Gerüst. Das Material nimmt Gäste größen- und enantioselektiv auf (siehe Bild) und zeigt eine bemerkenswerte größen- und chemoselektive katalytische Aktivität sowie einen hohen Umsatz bei der Oxidation von Thioethern zu Sulfoxiden.

Dybtsev D.N. , Nuzhdin A.L. , Chun H. , Bryliakov K.P. , Talsi E.P. , Fedin V.P. , Kim K.
A Homochiral Metal–Organic Material with Permanent Porosity, Enantioselective Sorption Properties, and Catalytic Activity
Angewandte Chemie (German edition). 2006. V.118. N6. P.930-934. DOI: 10.1002/ange.200503023 РИНЦ OpenAlex

Dybtsev D.N. , Nuzhdin A.L. , Chun H. , Bryliakov K.P. , Talsi E.P. , Fedin V.P. , Kim K.
A Homochiral Metal-Organic Material with Permanent Porosity, Enantioselective Sorption Properties, and Catalytic Activity
Angewandte Chemie - International Edition. 2006. V.45. N6. P.916-920. DOI: 10.1002/anie.200503023 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	24 авг. 2005 г.
Принята к публикации:	10 окт. 2005 г.
Опубликована online:	30 дек. 2005 г.
Опубликована в печати:	23 янв. 2006 г.

РИНЦ:	26578091
OpenAlex:	W4254364902

БД	Цитирований
РИНЦ	67
OpenAlex	110