A Homochiral Metal–Organic Material with Permanent Porosity, Enantioselective Sorption Properties, and Catalytic Activity | Sciact - CRIS-system of Boreskov Institute of Catalysis

A Homochiral Metal–Organic Material with Permanent Porosity, Enantioselective Sorption Properties, and Catalytic Activity Full article

Journal

Angewandte Chemie (German edition)
ISSN: 0044-8249 , E-ISSN: 1521-3757

Output data

Year: 2006, Volume: 118, Number: 6, Pages: 930-934 Pages count : 5 DOI: 10.1002/ange.200503023

Tags

Chirality; Heterogeneous catalysis; Metal-organic frameworks; Microporous materials; Sorption

Authors

Dybtsev Danil N. ^1,2 , Nuzhdin Alexey L. ³ , Chun Hyungphil ¹ , Bryliakov Konstantin P. ³ , Talsi Evgeniy P. ³ , Fedin Vladimir P. ² , Kim Kimoon ¹

Affiliations

1	National Creative Research Initiative Center for Smart Supramolecules and Department of Chemistry Division of Molecular and Life Sciences, Pohang University of Science and Technology, San 31 Hyojadong, Pohang 790-784 (Republic of Korea)
2	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Pr. Lavrentieva 3, Novosibirsk 630090 (Russia)
3	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences. Pr. Lavrentieva 5, Novosibirsk 630090 (Russia)

Funding (2)

1	Russian Foundation for Basic Research	03-03-32009
2	Council for Grants of the President of the Russian Federation	МК-3842.2004.3

A new synthetic approach starting from readily available chemicals successfully produces a robust homochiral metal–organic microporous framework. The material exhibits size- and enantioselective guest-sorption properties (see picture), as well as remarkable catalytic activity with size- and chemoselectivity, and high conversion in the oxidation of thioethers to sulfoxides. Ein neuer Syntheseansatz, der von einfach verfügbaren Chemikalien ausgeht, liefert ein robustes homochirales mikroporöses metall-organisches Gerüst. Das Material nimmt Gäste größen- und enantioselektiv auf (siehe Bild) und zeigt eine bemerkenswerte größen- und chemoselektive katalytische Aktivität sowie einen hohen Umsatz bei der Oxidation von Thioethern zu Sulfoxiden.

Dybtsev D.N. , Nuzhdin A.L. , Chun H. , Bryliakov K.P. , Talsi E.P. , Fedin V.P. , Kim K.
A Homochiral Metal–Organic Material with Permanent Porosity, Enantioselective Sorption Properties, and Catalytic Activity
Angewandte Chemie (German edition). 2006. V.118. N6. P.930-934. DOI: 10.1002/ange.200503023 РИНЦ OpenAlex

Dybtsev D.N. , Nuzhdin A.L. , Chun H. , Bryliakov K.P. , Talsi E.P. , Fedin V.P. , Kim K.
A Homochiral Metal-Organic Material with Permanent Porosity, Enantioselective Sorption Properties, and Catalytic Activity
Angewandte Chemie - International Edition. 2006. V.45. N6. P.916-920. DOI: 10.1002/anie.200503023 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Aug 24, 2005
Accepted:	Oct 10, 2005
Published online:	Dec 30, 2005
Published print:	Jan 23, 2006

Elibrary:	26578091
OpenAlex:	W4254364902

DB	Citing
Elibrary	67
OpenAlex	110