Catalytic Properties of Palladium Nanoparticles Deposited on Undoped and Nitrogen Doped Carbon Nanofibres in Selective Hydrogenation of Acetylene | Sciact - CRIS-система Института катализа

Catalytic Properties of Palladium Nanoparticles Deposited on Undoped and Nitrogen Doped Carbon Nanofibres in Selective Hydrogenation of Acetylene Научная публикация

Журнал

Химия в интересах устойчивого развития
ISSN: 0869-8538

Вых. Данные

Год: 2016, Том: 24, Номер: 4, Страницы: 521-527 Страниц : 7 DOI: 10.15372/KhUR20160412

Ключевые слова

PALLADIUM NANOPARTICLES, CARBON NANOFIBRES, NITROGEN DOPING, HYDROGENATION

Авторы

Chesnokov Vladimir V. ^1,2 , Podyacheva Olga Yu. ^1,2 , Ismagilov Zinfer R. ^1,2

Организации

1	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2	Institute of Coal Chemistry and Material Science, Federal Research Center of Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences, Kemerovo, Russia

Информация о финансировании (1)

Российский научный фонд

15-13-10043

Palladium in the concentration of 0.04-0.5 mass % was deposited on carbon nanofibres with the stack structure. The state of finely dispersed palladium nanoparticles deposited on the carbon nanofibres was studied by physical methods. Decrease of the concentration of supported palladium on the carbon nanofibres below 0.2 mass % led to the stabilization of the metal in atomic state. It was found that palladium nanoparticles in the atomic state were responsible for the high selectivity of the catalyst in acetylene hydrogenation to ethylene. Doping of carbon nanofibres by nitrogen atoms substantially alters the properties of supported palladium nanoparticles. The activity of the catalysts decreases whereas their selectivity substantially increases

Chesnokov V.V. , Podyacheva O.Y. , Ismagilov Z.R.
Catalytic Properties of Palladium Nanoparticles Deposited on Undoped and Nitrogen Doped Carbon Nanofibres in Selective Hydrogenation of Acetylene
Химия в интересах устойчивого развития. 2016. V.24. N4. P.521-527. DOI: 10.15372/KhUR20160412RSCI РИНЦ CAPlusCA OpenAlex

Russian Science Citation Index (RSCI):	RSCI:26511013
РИНЦ:	26511013
Chemical Abstracts:	2017:131283
Chemical Abstracts (print):	167:118255
OpenAlex:	W4230229848

БД	Цитирований
РИНЦ	2
OpenAlex	1