Catalytic Properties of Palladium Nanoparticles Deposited on Undoped and Nitrogen Doped Carbon Nanofibres in Selective Hydrogenation of Acetylene Full article
| Journal |
Химия в интересах устойчивого развития
ISSN: 0869-8538 |
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| Output data | Year: 2016, Volume: 24, Number: 4, Pages: 521-527 Pages count : 7 DOI: 10.15372/KhUR20160412 | ||||
| Tags | PALLADIUM NANOPARTICLES, CARBON NANOFIBRES, NITROGEN DOPING, HYDROGENATION | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Science Foundation | 15-13-10043 |
Abstract:
Palladium in the concentration of 0.04-0.5 mass % was deposited on carbon nanofibres with the stack structure. The state of finely dispersed palladium nanoparticles deposited on the carbon nanofibres was studied by physical methods. Decrease of the concentration of supported palladium on the carbon nanofibres below 0.2 mass % led to the stabilization of the metal in atomic state. It was found that palladium nanoparticles in the atomic state were responsible for the high selectivity of the catalyst in acetylene hydrogenation to ethylene. Doping of carbon nanofibres by nitrogen atoms substantially alters the properties of supported palladium nanoparticles. The activity of the catalysts decreases whereas their selectivity substantially increases
Cite:
Chesnokov V.V.
, Podyacheva O.Y.
, Ismagilov Z.R.
Catalytic Properties of Palladium Nanoparticles Deposited on Undoped and Nitrogen Doped Carbon Nanofibres in Selective Hydrogenation of Acetylene
Химия в интересах устойчивого развития. 2016. V.24. N4. P.521-527. DOI: 10.15372/KhUR20160412RSCI РИНЦ ANCAN OpenAlex
Catalytic Properties of Palladium Nanoparticles Deposited on Undoped and Nitrogen Doped Carbon Nanofibres in Selective Hydrogenation of Acetylene
Химия в интересах устойчивого развития. 2016. V.24. N4. P.521-527. DOI: 10.15372/KhUR20160412RSCI РИНЦ ANCAN OpenAlex
Identifiers:
| RSCI: | RSCI:26511013 |
| Elibrary: | 26511013 |
| Chemical Abstracts: | 2017:131283 |
| Chemical Abstracts (print): | 167:118255 |
| OpenAlex: | W4230229848 |