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Separation of Phenol-Containing Pyrolysis Products Using Comprehensive Two-Dimensional Chromatography with Columns Based on Pyridinium Ionic Liquids Научная публикация

Журнал Journal of Separation Science
ISSN: 1615-9306 , E-ISSN: 1615-9314
Вых. Данные Год: 2016, Том: 39, Номер: 19, Страницы: 3754-3760 Страниц : 7 DOI: 10.1002/jssc.201600431
Ключевые слова Bio-oil, Comprehensive two-dimensional chromatography, Ionic liquids, Polar stationary phases
Авторы Shashkov Mikhail V. 1,2 , Sidelnikov Vladimir N. 1,2
Организации
1 Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russian Federation
2 Novosibirsk State University, Novosibirsk, Russian Federation

Реферат: We describe the application of columns with highly polar stationary liquid phases based on pyridinium ionic liquids for the two-dimensional chromatography separation of bio-oil and product of coal pyrolysis. By using inverse combination columns—a first ionic liquid column and a second nonpolar column—good separation results have been obtained. In the analysis of coal pyrolysis products, the suggested approach provides a much better resolution between components in comparison with a less polar first-dimension column (based on polyethylene glycol). A good selectivity for the peaks of phenols is observed, and the group of phenols is well detached and separated from the group of diaromatics. A good separation picture was obtained also for bio-oil, the groups of phenols and guaiacol derivatives are distinguished with good resolution of substances within each group.
Библиографическая ссылка: Shashkov M.V. , Sidelnikov V.N.
Separation of Phenol-Containing Pyrolysis Products Using Comprehensive Two-Dimensional Chromatography with Columns Based on Pyridinium Ionic Liquids
Journal of Separation Science. 2016. V.39. N19. P.3754-3760. DOI: 10.1002/jssc.201600431 WOS Scopus РИНЦ CAPlus PMID OpenAlex
Даты:
Поступила в редакцию: 14 апр. 2016 г.
Принята к публикации: 28 июл. 2016 г.
Опубликована online: 5 авг. 2016 г.
Опубликована в печати: 1 окт. 2016 г.
Идентификаторы БД:
Web of science: WOS:000389044300012
Scopus: 2-s2.0-84990251362
РИНЦ: 27579975
Chemical Abstracts: 2016:1303057
PMID (PubMed): 27494745
OpenAlex: W2462354120
Цитирование в БД:
БД Цитирований
Web of science 15
Scopus 17
РИНЦ 18
OpenAlex 20
Альметрики: