Abstract: We describe the application of columns with highly polar stationary liquid phases based on pyridinium ionic liquids for the two-dimensional chromatography separation of bio-oil and product of coal pyrolysis. By using inverse combination columns—a first ionic liquid column and a second nonpolar column—good separation results have been obtained. In the analysis of coal pyrolysis products, the suggested approach provides a much better resolution between components in comparison with a less polar first-dimension column (based on polyethylene glycol). A good selectivity for the peaks of phenols is observed, and the group of phenols is well detached and separated from the group of diaromatics. A good separation picture was obtained also for bio-oil, the groups of phenols and guaiacol derivatives are distinguished with good resolution of substances within each group.

Cite: Shashkov M.V. , Sidelnikov V.N.
Separation of Phenol-Containing Pyrolysis Products Using Comprehensive Two-Dimensional Chromatography with Columns Based on Pyridinium Ionic Liquids
Journal of Separation Science. 2016. V.39. N19. P.3754-3760. DOI: 10.1002/jssc.201600431 WOS Scopus РИНЦ AN PMID OpenAlex

Dates:

Submitted:	Apr 14, 2016
Accepted:	Jul 28, 2016
Published online:	Aug 5, 2016
Published print:	Oct 1, 2016

Identifiers:

Web of science:	WOS:000389044300012
Scopus:	2-s2.0-84990251362
Elibrary:	27579975
Chemical Abstracts:	2016:1303057
PMID:	27494745
OpenAlex:	W2462354120

Citing:

DB	Citing
Web of science	16
Scopus	17
Elibrary	18
OpenAlex	20

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