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Direct Selective Oxidative Functionalization of C–H Bonds with H2O2: Mn-Aminopyridine Complexes Challenge the Dominance of Non-Heme Fe Catalysts Обзор

Журнал Molecules
ISSN: 1420-3049
Вых. Данные Год: 2016, Том: 21, Номер: 11, Номер статьи : 1454, Страниц : 16 DOI: 10.3390/molecules21111454
Ключевые слова C-H functionalization, Enzyme models, Hydrogen peroxide, Manganese, Mechanism, Oxidation
Авторы Ottenbacher Roman V. 1,2 , Talsi Evgenii P. 1,2 , Bryliakov Konstantin P. 1,2
Организации
1 Chemistry Department, Novosibirsk State University, Pirogova 2, Novosibirsk 630090, Russia
2 Boreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090, Russia

Информация о финансировании (2)

1 Федеральное агентство научных организаций России V.44.2.4.
2 Российский фонд фундаментальных исследований 16-29-10666

Реферат: Non-heme iron(II) complexes are widespread synthetic enzyme models, capable of conducting selective C–H oxidation with H2O2 in the presence of carboxylic acid additives. In the last years, structurally similar manganese(II) complexes have been shown to catalyze C–H oxidation with similarly high selectivity, and with much higher efficiency. In this mini-review, recent catalytic and mechanistic data on the selective C–H oxygenations with H2O2 in the presence of manganese complexes are overviewed. A distinctive feature of catalyst systems of the type Mn complex/H2O2/carboxylic is the existence of two alternative reaction pathways (as found for the oxidation of cumenes), one leading to the formation of alcohol, and the other to ester. The mechanisms of formation of the alcohol and the ester are briefly discussed
Библиографическая ссылка: Ottenbacher R.V. , Talsi E.P. , Bryliakov K.P.
Direct Selective Oxidative Functionalization of C–H Bonds with H2O2: Mn-Aminopyridine Complexes Challenge the Dominance of Non-Heme Fe Catalysts
Molecules. 2016. V.21. N11. 1454 :1-16. DOI: 10.3390/molecules21111454 WOS Scopus РИНЦ CAPlusCA PMID OpenAlex
Файлы: Полный текст от издателя
Даты:
Поступила в редакцию: 28 сент. 2016 г.
Принята к публикации: 20 окт. 2016 г.
Опубликована online: 31 окт. 2016 г.
Опубликована в печати: 1 нояб. 2016 г.
Идентификаторы БД:
Web of science: WOS:000389918200036
Scopus: 2-s2.0-84994043920
РИНЦ: 31037396
Chemical Abstracts: 2016:2140199
Chemical Abstracts (print): 166:155698
PMID (PubMed): 27809257
OpenAlex: W2540880389
Цитирование в БД:
БД Цитирований
Web of science 33
Scopus 34
РИНЦ 34
OpenAlex 38
Альметрики: