Direct Selective Oxidative Functionalization of C–H Bonds with H2O2: Mn-Aminopyridine Complexes Challenge the Dominance of Non-Heme Fe Catalysts Обзор
| Журнал |
Molecules
ISSN: 1420-3049 |
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| Вых. Данные | Год: 2016, Том: 21, Номер: 11, Номер статьи : 1454, Страниц : 16 DOI: 10.3390/molecules21111454 | ||||
| Ключевые слова | C-H functionalization, Enzyme models, Hydrogen peroxide, Manganese, Mechanism, Oxidation | ||||
| Авторы |
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| Организации |
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Информация о финансировании (2)
| 1 | Российский фонд фундаментальных исследований | 16-29-10666 |
| 2 | Федеральное агентство научных организаций России | V.44.2.4. |
Реферат:
Non-heme iron(II) complexes are widespread synthetic enzyme models, capable of conducting selective C–H oxidation with H2O2 in the presence of carboxylic acid additives. In the last years, structurally similar manganese(II) complexes have been shown to catalyze C–H oxidation with similarly high selectivity, and with much higher efficiency. In this mini-review, recent catalytic and mechanistic data on the selective C–H oxygenations with H2O2 in the presence of manganese complexes are overviewed. A distinctive feature of catalyst systems of the type Mn complex/H2O2/carboxylic is the existence of two alternative reaction pathways (as found for the oxidation of cumenes), one leading to the formation of alcohol, and the other to ester. The mechanisms of formation of the alcohol and the ester are briefly discussed.
Библиографическая ссылка:
Ottenbacher R.V.
, Talsi E.P.
, Bryliakov K.P.
Direct Selective Oxidative Functionalization of C–H Bonds with H2O2: Mn-Aminopyridine Complexes Challenge the Dominance of Non-Heme Fe Catalysts
Molecules. 2016.
V.21. N11. 1454
:1-16. DOI: 10.3390/molecules21111454
WOS
Scopus
РИНЦ
OpenAlex
CAPlusCA
PMID
Direct Selective Oxidative Functionalization of C–H Bonds with H2O2: Mn-Aminopyridine Complexes Challenge the Dominance of Non-Heme Fe Catalysts
Molecules. 2016.
V.21. N11. 1454
:1-16. DOI: 10.3390/molecules21111454
WOS
Scopus
РИНЦ
OpenAlex
CAPlusCA
PMID
Файлы:
Полный текст от издателя
Даты:
| Поступила в редакцию: | 28 сент. 2016 г. |
| Принята к публикации: | 20 окт. 2016 г. |
| Опубликована online: | 31 окт. 2016 г. |
| Опубликована в печати: | 1 нояб. 2016 г. |
Идентификаторы БД:
| ≡ Web of science: | WOS:000389918200036 |
| ≡ Scopus: | 2-s2.0-84994043920 |
| ≡ РИНЦ: | 31037396 |
| ≡ OpenAlex: | W2540880389 |
| ≡ Chemical Abstracts: | 2016:2140199 |
| ≡ Chemical Abstracts (print): | 166:155698 |
| ≡ PMID (PubMed): | 27809257 |