Direct Selective Oxidative Functionalization of C–H Bonds with H2O2: Mn-Aminopyridine Complexes Challenge the Dominance of Non-Heme Fe Catalysts Review
| Journal |
Molecules
ISSN: 1420-3049 |
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| Output data | Year: 2016, Volume: 21, Number: 11, Article number : 1454, Pages count : 16 DOI: 10.3390/molecules21111454 | ||||
| Tags | C-H functionalization, Enzyme models, Hydrogen peroxide, Manganese, Mechanism, Oxidation | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Federal Agency for Scientific Organizations | V.44.2.4. |
| 2 | Russian Foundation for Basic Research | 16-29-10666 |
Abstract:
Non-heme iron(II) complexes are widespread synthetic enzyme models, capable of conducting selective C–H oxidation with H2O2 in the presence of carboxylic acid additives. In the last years, structurally similar manganese(II) complexes have been shown to catalyze C–H oxidation with similarly high selectivity, and with much higher efficiency. In this mini-review, recent catalytic and mechanistic data on the selective C–H oxygenations with H2O2 in the presence of manganese complexes are overviewed. A distinctive feature of catalyst systems of the type Mn complex/H2O2/carboxylic is the existence of two alternative reaction pathways (as found for the oxidation of cumenes), one leading to the formation of alcohol, and the other to ester. The mechanisms of formation of the alcohol and the ester are briefly discussed
Cite:
Ottenbacher R.V.
, Talsi E.P.
, Bryliakov K.P.
Direct Selective Oxidative Functionalization of C–H Bonds with H2O2: Mn-Aminopyridine Complexes Challenge the Dominance of Non-Heme Fe Catalysts
Molecules. 2016.
V.21. N11. 1454
:1-16. DOI: 10.3390/molecules21111454
WOS
Scopus
РИНЦ
ANCAN
PMID
OpenAlex
Direct Selective Oxidative Functionalization of C–H Bonds with H2O2: Mn-Aminopyridine Complexes Challenge the Dominance of Non-Heme Fe Catalysts
Molecules. 2016.
V.21. N11. 1454
:1-16. DOI: 10.3390/molecules21111454
WOS
Scopus
РИНЦ
ANCAN
PMID
OpenAlex
Files:
Full text from publisher
Dates:
| Submitted: | Sep 28, 2016 |
| Accepted: | Oct 20, 2016 |
| Published online: | Oct 31, 2016 |
| Published print: | Nov 1, 2016 |
Identifiers:
| Web of science: | WOS:000389918200036 |
| Scopus: | 2-s2.0-84994043920 |
| Elibrary: | 31037396 |
| Chemical Abstracts: | 2016:2140199 |
| Chemical Abstracts (print): | 166:155698 |
| PMID: | 27809257 |
| OpenAlex: | W2540880389 |