Kinetic Studies of Methanol Dehydrogenation. Part III: Carbon-Supported Copper Catalysts Научная публикация
| Журнал |
Reaction Kinetics, Mechanisms and Catalysis
ISSN: 1878-5190 , E-ISSN: 1878-5204 |
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| Вых. Данные | Год: 2017, Том: 122, Номер: 1, Страницы: 385-398 Страниц : 14 DOI: 10.1007/s11144-017-1214-y | ||||
| Ключевые слова | Carbon-supported copper catalysts, Kinetics, Methanol dehydrogenation, Methyl formate, Rate constants, Sibunit | ||||
| Авторы |
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| Организации |
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Информация о финансировании (2)
| 1 | Федеральное агентство научных организаций России | 0303-2016-0014 |
| 2 | Российский фонд фундаментальных исследований | 16-38-00095 |
Реферат:
Kinetics of methanol dehydrogenation reaction over carbon-supported copper catalyst was studied. The catalyst was prepared by incipient wetness impregnation of carbonaceous graphite-like material Sibunit with aqueous solution of copper nitrate. Resulting Cu/C samples were calcined and reduced in a hydrogen flow within temperature interval of 200-400 °C. Experiments were carried out in a flow-through fixed-bed tubular reactor. Observable rate constants were determined for the reactions of methanol dehydrogenation to methyl formate and methyl formate decomposition on carbon monoxide and hydrogen. The process of methanol dehydrogenation in tubular reactor was simulated by means of mathematical modeling. Estimation of kinetic parameters in accordance with experimental data obtained for the Cu/C sample reduced at 300 °C has allowed us to consider the reversibility of methanol dehydrogenation reaction.
Библиографическая ссылка:
Shelepova E.V.
, Ilina L.Y.
, Vedyagin A.A.
Kinetic Studies of Methanol Dehydrogenation. Part III: Carbon-Supported Copper Catalysts
Reaction Kinetics, Mechanisms and Catalysis. 2017. V.122. N1. P.385-398. DOI: 10.1007/s11144-017-1214-y WOS Scopus РИНЦ OpenAlex CAPlusCA
Kinetic Studies of Methanol Dehydrogenation. Part III: Carbon-Supported Copper Catalysts
Reaction Kinetics, Mechanisms and Catalysis. 2017. V.122. N1. P.385-398. DOI: 10.1007/s11144-017-1214-y WOS Scopus РИНЦ OpenAlex CAPlusCA
Даты:
| Поступила в редакцию: | 3 мая 2017 г. |
| Принята к публикации: | 9 июн. 2017 г. |
| Опубликована online: | 14 июн. 2017 г. |
| Опубликована в печати: | 1 окт. 2017 г. |
Идентификаторы БД:
| ≡ Web of science: | WOS:000408706800027 |
| ≡ Scopus: | 2-s2.0-85020754367 |
| ≡ РИНЦ: | 31022546 |
| ≡ OpenAlex: | W2625099921 |
| ≡ Chemical Abstracts: | 2017:1002060 |
| ≡ Chemical Abstracts (print): | 168:358741 |