Kinetic Studies of Methanol Dehydrogenation. Part III: Carbon-Supported Copper Catalysts Full article
| Journal |
Reaction Kinetics, Mechanisms and Catalysis
ISSN: 1878-5190 , E-ISSN: 1878-5204 |
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| Output data | Year: 2017, Volume: 122, Number: 1, Pages: 385-398 Pages count : 14 DOI: 10.1007/s11144-017-1214-y | ||||
| Tags | Carbon-supported copper catalysts, Kinetics, Methanol dehydrogenation, Methyl formate, Rate constants, Sibunit | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0014 |
| 2 | Russian Foundation for Basic Research | 16-38-00095 |
Abstract:
Kinetics of methanol dehydrogenation reaction over carbon-supported copper catalyst was studied. The catalyst was prepared by incipient wetness impregnation of carbonaceous graphite-like material Sibunit with aqueous solution of copper nitrate. Resulting Cu/C samples were calcined and reduced in a hydrogen flow within temperature interval of 200-400 °C. Experiments were carried out in a flow-through fixed-bed tubular reactor. Observable rate constants were determined for the reactions of methanol dehydrogenation to methyl formate and methyl formate decomposition on carbon monoxide and hydrogen. The process of methanol dehydrogenation in tubular reactor was simulated by means of mathematical modeling. Estimation of kinetic parameters in accordance with experimental data obtained for the Cu/C sample reduced at 300 °C has allowed us to consider the reversibility of methanol dehydrogenation reaction.
Cite:
Shelepova E.V.
, Ilina L.Y.
, Vedyagin A.A.
Kinetic Studies of Methanol Dehydrogenation. Part III: Carbon-Supported Copper Catalysts
Reaction Kinetics, Mechanisms and Catalysis. 2017. V.122. N1. P.385-398. DOI: 10.1007/s11144-017-1214-y WOS Scopus РИНЦ ANCAN OpenAlex
Kinetic Studies of Methanol Dehydrogenation. Part III: Carbon-Supported Copper Catalysts
Reaction Kinetics, Mechanisms and Catalysis. 2017. V.122. N1. P.385-398. DOI: 10.1007/s11144-017-1214-y WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | May 3, 2017 |
| Accepted: | Jun 9, 2017 |
| Published online: | Jun 14, 2017 |
| Published print: | Oct 1, 2017 |
Identifiers:
| Web of science: | WOS:000408706800027 |
| Scopus: | 2-s2.0-85020754367 |
| Elibrary: | 31022546 |
| Chemical Abstracts: | 2017:1002060 |
| Chemical Abstracts (print): | 168:358741 |
| OpenAlex: | W2625099921 |