Pulse Microcalorimetry Study of Methane Dry Reforming Reaction on Ni/Ceria-Zirconia Catalyst Научная публикация
Журнал |
Catalysts
ISSN: 2073-4344 |
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Вых. Данные | Год: 2017, Том: 7, Номер: 9, Номер статьи : 268, Страниц : 11 DOI: 10.3390/catal7090268 | ||||
Ключевые слова | Ceria-zirconia, Mechanism, Methane dry reforming, Pulse microcalorimetry, Synthesis in supercritical alcohol | ||||
Авторы |
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Организации |
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Информация о финансировании (1)
1 | Министерство образования и науки Российской Федерации | 14.616.21.0036 |
Реферат:
For Ni/CeZrO catalyst prepared in supercritical isopropanol main features of methane dry reforming reaction mechanism were studied by the pulse microcalorimetric technique. The reaction scheme is described by a step-wise redox mechanism with independent stages of CH4 transformation on Ni/support interface producing syngas with participation of support oxygen bridging species (the rate-limiting stage) and fast reoxidation of support sites by CO2 yielding CO regenerating reactive oxygen species.
Библиографическая ссылка:
Simonov M.N.
, Rogov V.A.
, Smirnova M.Y.
, Sadykov V.A.
Pulse Microcalorimetry Study of Methane Dry Reforming Reaction on Ni/Ceria-Zirconia Catalyst
Catalysts. 2017. V.7. N9. 268 :1-11. DOI: 10.3390/catal7090268 WOS Scopus РИНЦ CAPlusCA OpenAlex
Pulse Microcalorimetry Study of Methane Dry Reforming Reaction on Ni/Ceria-Zirconia Catalyst
Catalysts. 2017. V.7. N9. 268 :1-11. DOI: 10.3390/catal7090268 WOS Scopus РИНЦ CAPlusCA OpenAlex
Файлы:
Полный текст от издателя
Даты:
Поступила в редакцию: | 24 авг. 2017 г. |
Принята к публикации: | 7 сент. 2017 г. |
Опубликована в печати: | 12 сент. 2017 г. |
Опубликована online: | 12 сент. 2017 г. |
Идентификаторы БД:
Web of science: | WOS:000411566400025 |
Scopus: | 2-s2.0-85029458168 |
РИНЦ: | 31036334 |
Chemical Abstracts: | 2017:1713073 |
Chemical Abstracts (print): | 168:474719 |
OpenAlex: | W2755803345 |