Pulse Microcalorimetry Study of Methane Dry Reforming Reaction on Ni/Ceria-Zirconia Catalyst | Sciact - CRIS-system of Boreskov Institute of Catalysis

Pulse Microcalorimetry Study of Methane Dry Reforming Reaction on Ni/Ceria-Zirconia Catalyst Full article

Journal

Catalysts
ISSN: 2073-4344

Output data

Year: 2017, Volume: 7, Number: 9, Article number : 268, Pages count : 11 DOI: 10.3390/catal7090268

Tags

Ceria-zirconia, Mechanism, Methane dry reforming, Pulse microcalorimetry, Synthesis in supercritical alcohol

Authors

Simonov Mikhail N. ^1,2 , Rogov Vladimir A. ^1,2 , Smirnova Marina Yu. ^1,2 , Sadykov Vladislav A. ^1,2

Affiliations

1	Boreskov Institute of Catalysis, Prospekt Akademika Lavrentieva, 5, Novosibirsk 630090, Russia
2	Novosibirsk State University, Pirogova Street, 2, Novosibirsk 630090, Russia

Funding (1)

The Ministry of Education and Science of the Russian Federation

14.616.21.0036

For Ni/CeZrO catalyst prepared in supercritical isopropanol main features of methane dry reforming reaction mechanism were studied by the pulse microcalorimetric technique. The reaction scheme is described by a step-wise redox mechanism with independent stages of CH4 transformation on Ni/support interface producing syngas with participation of support oxygen bridging species (the rate-limiting stage) and fast reoxidation of support sites by CO2 yielding CO regenerating reactive oxygen species.

Simonov M.N. , Rogov V.A. , Smirnova M.Y. , Sadykov V.A.
Pulse Microcalorimetry Study of Methane Dry Reforming Reaction on Ni/Ceria-Zirconia Catalyst

Catalysts. 2017. V.7. N9. 268 :1-11. DOI: 10.3390/catal7090268 WOS Scopus РИНЦ ANCAN OpenAlex

Full text from publisher

Submitted:	Aug 24, 2017
Accepted:	Sep 7, 2017
Published print:	Sep 12, 2017
Published online:	Sep 12, 2017

Web of science:	WOS:000411566400025
Scopus:	2-s2.0-85029458168
Elibrary:	31036334
Chemical Abstracts:	2017:1713073
Chemical Abstracts (print):	168:474719
OpenAlex:	W2755803345

DB	Citing
Web of science	14
Scopus	15
Elibrary	13
OpenAlex	14