New Methods for the Preparation of High-Octane Components from Ccatalytic Cracking Olefins | Sciact - CRIS-система Института катализа

New Methods for the Preparation of High-Octane Components from Ccatalytic Cracking Olefins Научная публикация

Журнал

Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555

Вых. Данные

Год: 2017, Том: 9, Номер: 3, Страницы: 204-211 Страниц : 8 DOI: 10.1134/S2070050417030060

Ключевые слова

alcohols, carbonyl compounds, ethers, high-octane component, hydrogenation of carbonyl compounds, ketones, octane number, oxidation of olefins

Авторы

Kharitonov A.S. ¹ , Ivanov D.P. ¹ , Parfenov M.V. ¹ , Piryutko L.V. ¹ , Semikolenov S.V. ¹ , Dubkov K.A. ¹ , Pereima V.Yu. ¹ , Noskov A.S. ¹ , Kondrashev D.O. ² , Kleymenov A.V. ² , Vedernikov O.S. ² , Kuznetsov S.E. ³ , Galkin V.V. ³ , Abrashenkov P.A. ³

Организации

1	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
2	Gazprom Neft, St. Petersburg, 190000 Russia
3	Gazpromneft-MNPZ, Moscow, 109429 Russia

Информация о финансировании (3)

1	Федеральное агентство научных организаций России	V.44.2.3.
2	Газпромнефть - Московский НПЗ	210777/45 и 210777/55 (МНЗ: №14/08000/00192/Р)
3	Газпром нефть

A new method has been suggested for the preparation of high-octane components from the butane–butylene fraction (BBF) in two stages. At the first stage, the BBF olefins are oxidized with N2O into carbonyl compounds with high selectivity without forming the products of deep oxidation and water. The process occurs in the gas phase in a flow reactor without using a catalyst at a temperature of 400°C and a pressure of 2 MPa with high conversion of both olefins and nitrous oxide. The blending octane number of the oxidation product is 118–133 (RON) and 99–104 (MON). At the second stage, the mixture of carbonyl compounds is hydrogenated with hydrogen in the presence of the Ni/Al2O3 catalyst. The hydrogenation occurs at 150–160°C in a flow reactor in the gas phase. The aldehydes are completely transformed into alcohols, while the ketones can remain in the product under certain conditions. The blending octane number of the hydrogenation product is 111–112 (RON) and 95–96 (MON), which is smaller than for the BBF oxidation product, but larger than for the alkylate obtained in the course of conventional butene alkylation with isobutane (RON is 95–97 and MON is 93–95). Synthesis of high-octane components by this procedure can be useful in practice, especially in productions with huge release of nitrous oxide.

Kharitonov A.S. , Ivanov D.P. , Parfenov M.V. , Piryutko L.V. , Semikolenov S.V. , Dubkov K.A. , Pereima V.Y. , Noskov A.S. , Kondrashev D.O. , Kleymenov A.V. , Vedernikov O.S. , Kuznetsov S.E. , Galkin V.V. , Abrashenkov P.A.
New Methods for the Preparation of High-Octane Components from Ccatalytic Cracking Olefins
Catalysis in Industry. 2017. V.9. N3. P.204-211. DOI: 10.1134/S2070050417030060 WOS Scopus РИНЦ OpenAlex

Харитонов А.С. , Иванов Д.П. , Парфенов М.В. , Пирютко Л.В. , Семиколенов С.В. , Дубков К.А. , Перейма В.Ю. , Носков А.С. , Кондрашев Д.О. , Клейменов А.В. , Ведерников О.С. , Кузнецов С.Е. , Галкин В.В. , Абрашенков П.А.
Новые способы получения высокооктановых компонентов из олефинов каталитического крекинга
Катализ в промышленности. 2016. №6. С.48-56. DOI: 10.18412/1816-0387-2016-6-48-56 РИНЦ OpenAlex

Поступила в редакцию:	3 окт. 2016 г.
Опубликована в печати:	1 июл. 2017 г.
Опубликована online:	21 сент. 2017 г.

Web of science:	WOS:000423241700004
Scopus:	2-s2.0-85029757830
РИНЦ:	31059883
OpenAlex:	W2756058669

БД	Цитирований
Web of science	5
Scopus	5
РИНЦ	5
OpenAlex	5